Effect of Urease inhibitor compositions with improved comprising hexamethylphosphoric (Uncle) Phosphoric acid and other compounds such as amines and Dyes

摘要

Claim 1: A composition, comprising: (A) a mixture comprising at least one triamide of the (thio) phosphoric acid according to the general formula (1): R¹R²N-P (X) (NH₂) ₂ (1),where X is oxygen or sulfur; R¹ is a C₁₋₂₀-alkyl, C₃₋₂₀-cycloalkyl, C₆₋₂₀-aryl, or dialkylaminocarbonyl group; R² is H, or R¹ and R²,In addition to the nitrogen atoms that link them together, it defines a saturated or unsaturated aperiodic laser composed of five or six members, which optionally includes one or two additional heteroatoms selected from the nitrogen, oxygen and sulfur groups, and (L1) at least one amine selected from the (L10) group,(L11)(L12)(L13)(L14)(L15)(L16)(L17)(L18)(L19)(L20)(L21)(L22)(L23)(L24) and (L29);(L10) a crystalline tar under general formula (2),wherein the radicals are defined as follows: R¹ and R² are, simultaneously or each independently, hydrogen, C₁₋₁₂-alkyl, C₇₋₁₂-aralkyl, C₆₋₁₀-aryl, C₃₋₈-cycloalkyl or C₃₋ Linear or branched cycloalkyl, wherein, optionally, preferably, obligatorily, one or more CH₂ groups were replaced by O, NH or NR¹⁰;O nhr83044;a. Direct direct direct direct direct direct direct direct direct direct direct direct direct direct indirect indirect indirect indirect indirect indirect direct direct direct direct direct direct direct direct direct indirect indirect direct direct direct direct indirect indirect indirect A. one or more ch832222 groups changed to o, NH or nhr83044;(y) All values of; (d) one polymerization base price of polybromine; (d) all polymerization base prices derived therefrom; (d) general (3) from polymerization base,Each of these radicals is defined as follows: R1,R² and R⁵ are simultaneously or each independently hydrogen, C₁₋₁₂-alkyl, C₇₋₁₂-aralkyl, C₆₋₁₀-aryl, C₃₋₈-cycloalkyl or C o-cycloalkyl linear or branched, where, optionally , preferably, mandatory entity, one or more CH₂ groups were replaced by O, NH or NR¹⁰;Or two of the three R1 radicalsR² and R⁵ covalently join together to form a linear or branched C₁₋₁₂-alkyl, C₇₋₁₂-aralkyl, C₆₋₁₀-aryl, C₃₋₈-cycloalkyl or C₃₋₈-cycloalkyl, where, optionally , preferably, one or more CH₂ groups were necessarily replaced by O, NH or NR¹⁰,And the other three R1 radicals,R² and R⁵ is hydrogen, C₁₋₁₂-alkyl, C₇₋₁₂-aralkyl, C₆₋₁₀-aryl, C₃₋₈-cycloalkyl or C₃₋₈-cycloalkyl linear or branched, where, optionally, preferably, necessarily, one or more CH₂ groups were replaced by O, NH or NR¹⁰;a. 2222 group;R¹⁰ is linear or branched C₁₋₁₂-alkyl, C₇₋₁₂-aralkyl, C₆₋₁₀-aryl or C₃₋₈-cycloalkyl; a is a value of 2 to 5; b is a value from 2 to 12; e y is an index that can assume all values between 1 and b; (L12) polyetheramines according to the general formula (4),a. Each type of radical is defined as follows: R1 and R2 are hydrogen at the same time or c8321 respectively; necessary a. One or more ch832222 groups changed to o, NH or nhr83044;alternatively, R¹ and R² together represent C₁₋₁₂-alkyl, C₇₋₁₂-aralkyl, C₆₋₁₀-aryl, C₃₋₈-cycloalkyl or C₃₋₈-cycloalkyl linear or branched, where, optionally, preferably, obligatorily , one or more CH₂ groups were replaced by O, NH or NR¹⁰;R3...R⁴ and R⁵ are, simultaneously or each independently, hydrogen, C₁₋₁₂-alkyl, C₇₋₁₂-aralkyl, C₆₋₁₀-aryl, C₃₋₈-cycloalkyl or C₃₋₈-cycloalkyl linear or branched, where, optionally , preferably, obligatorily, one or more CH₂ groups were replaced by O, NH or NR¹⁰;a. Polybrominated diphenyl ether polymer ((501) polyethylene, polybrominated diphenyl ether polymer, polybrominated diphenyl ether polymer with polybrominated diphenyl ether content less than 13, (l502) production of polyethylene according to general formula (5),1. Its average molar mass (MW) is 200-2000000 g / mol, wherein r8311a R1 is independent;a. Hydrogen, c833218cf1833222;; 8320a tar, alcox, polyoxy, hydroxy, hydroxy - (TAR) carboxi, phosphorus, linear lease or separator, formamisay, pirroidni -,imidazolyl, C₂₋₂₀-alkenyl or C₆₋₂₀-aryl, -aryloxy, o-hydroxybenzoyl, phthalimidoyl, o-carboxamidobenzoyl, o- (C₁₋₈-alkoxycarbonyl) benzoyl, o-aminobenzoyl, or- (mono-C₁₋) radicals ₈-alkylamino) benzoyl, o- (di-C₁₋₈-alkylamino) benzoyl, 2-cyano-3,3-diphenylacryloyl, or m-benzimidazolyl-p-hydroxybenzoyl radicals, which can also be optionally substituted, where s an integer, t is 0 or an integer, where the sum of syt must be chosen such that the average molar mass is within the specified range, (L503) polyallylamine, (L504) poly (diallyldimethylammonium chloride),(L505) cationic polyvinylfomiamide, (L506) cationic polyvinylpyrrolidone, (L507) cationic polyvinyl acetamide, (L508) cationic polyvinylmethylformamide, (L509) cationic polyvinylmethylacetamide, (L510) poly (dimethylpropyl) poly (dimethylpropyl) dimethylamide(L511) poli (acrilato de dimetilaminoetilo)(L512) Poli (two ethyl acrylate),(l513) poly (acrylonitrile methyl ammonium chloride),(l514) poly,(L515) poli (cloruro de metacrilamidotripropiltrimetilamonio)(l516) polyacrylonitrile (l517) polyacrylonitrile (vinilpina),(L518) bromuro de hexadimetrina (L519) poli (dietilamina-co-epiclorohidrina)(L520) poli (dimetilamina-co-epiclorohidrina-co-etilendiamina)(L521) poli (amidoamina-epiclorohidrina)(l522) linear polyamide, branched or polypolyamide, or (l523) polyamide, with an average molecular weight (MW) of 1000-200000 g / mol, (l524) ionic starch, or polyamide containing N-vinyl formamide, alilamina, cloro de diarildemethylamonio, n-vinilpirolidona, n-metal-n-viniflforma, N-methyl-n-chloroacrylamine, dimethylacrylonitrile, dimethylaminoacetylacrylate, diethylmethylacrylonitrile or acrylonitrile acrylonitrile methylammonium chloride, when the polymer is the basic polymer, it shall be separated and separated in the form of polymer as required;(L14) polyethylene according to general formula (6);1. Its average molecular weight (MW) is 200-1000000 g / mol, wherein r1-r8310 is independent;hydrogen, C₁₋₂₀-alkyl, -alkoxy, -polyoxyalkylene, -polyoxyethylene, -hydroxyalkyl, - (alkyl) carboxy, -phosphonoalkyl, linear or branched alkylamino, C₂₋₂₀-alkenyl radicals or C₆₋₂₀-aryl radicals, -aryloxy, -hydroxyaryl, -arylcarboxy or -arylamino which are also optionally substituted, and additionally, each of R²,R3 and r83099 may be independent,a. Selective polyethylene chain, R1 can be a radical nra3 r830808 or a radical n832222;10. Y and Z are independent zeros or integers. When selecting the sum of X and Z, the average molecular weight must be within the specified range; (L15) according to the general formula (6) polyethylene.Among them, at least one ionosphere (L16) from R2 to r8310 is a polyoxy tar group; (L16) a polymer, which can be obtained by a process (l16p) including stage l16a: l16a. Condense at least one n - (hydroxy) amine (7) and / or (8) selected from the formula,wherein A is independently selected from C₁₋₆-alkylene; R¹,R1*,R2,R2*,R3,R3*,R830808,R830808*,R83099a and r83099a * are independently elected,e. The last three matrices are selected from hydrogen, tar, cyclopentyl or arilo, and hydrogen, tar, cyclopentyl or arilo are selected as alternatives; (L17) polymer (l17p) available in the process,There are two steps l17a and l17b: l17a selects at least one n - (hydroxy) amine (7) and / or (8) from the formula for condensation,wherein A is independently selected from C₁₋₆-alkylene; R¹,R1*,R2,R2*,R3,R3*,R830808,R830808*,R83099a and r83099a * are independently elected,e. The last three groups mentioned above can be replaced by hydrogen, tar, cyclopentyl or arilo; r8310 can be replaced by hydrogen, tar, cyclopentyl or arilo; and l17b) make at least part of the remaining hydrogen Xi group react and / or in the case of such reaction, 1. At least a part of the secondary polyether amine group supplied by L17 a contains at least one oxidized tar; (L18) a derivative, which can be obtained by tetraethylation, protonation, sulfate and / or phosphate (L16) or (L17) of the polymer;(L19) dendritic polyamines or their precursors selected from (L554) N, N, N, N-tetraaminopropylalkylenediamine, (L555) dendritic amine which can be obtained from N, N, N, N-tetraaminopropylalkylenediamine by amino-n-propylation (by example, known as N14-,N30...N62 and n128-amina, depending on the number of nitrogen atoms,(L556) N, N, N, N-tetraaminopropylethylenediamine, (L557) dendritic amines that can be obtained from N, N, N, N-tetraaminopropylethylenediamine by amino-n-propylation (for example, known as N14-,N30...N62 and n128-amina, depending on the number of nitrogen atoms,(L558) N, N, N, N-tetraaminopropylpropylenediamine, (L559) dendritic amines that can be obtained from N, N, N, N-tetraaminopropylpropylenediamine by amino-n-propylation (for example, known as N14-,N30...N62 and n128-amina, depending on the number of nitrogen atoms,(L560) N, N, N, N-tetraaminopropylbutylenediamine, (L561) dendritic amines that can be obtained from N, N, N, N-tetraaminopropylbutylenediamine by amino-n-propylation (for example, known as N14-,N30...a. N62 - and n128-amina, calculated according to the number of nitrogen atoms;(L20) una poliamina bic clica tric clica o polic clica mayor (L21) una amina que contiene no ms de un grupo amino y dos grupos R -C -alquilo sustituidos con alcoxi o hidroxi y un grupo R -C -alquilo en donde el (L23) n-nitroformate in one or two nitrogen atoms is replaced by tar with 2-cm3 group, in which 3-can be replaced by OH group; (L24) morphine n-can be replaced by R 83088 tar group, where it can be replaced by amino acid homopolymer with OH group (L29); 11. Claim 2: the composition conforming to claim 1, i.e. mixture (a) comprises n-n-butilifoforico (NPT) triethylamine and / or n-n-propiltifo (nppt) triethylamine.