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Carbon fibers coated with a bonding agent, process for production of the carbon fibre prepreg and composite material reinforced with carbon fibers

机译:涂有粘合剂的碳纤维,碳纤维预浸料的生产方法以及用碳纤维增强的复合材料

摘要

Provided are sizing agent-coated carbon fibers that achieve excellent adhesion between the carbon fibers and a matrix resin and yield a prepreg having excellent stability of composite physical properties after long-term storage and having excellent high-order processability, a process for producing the sizing agent-coated carbon fibers, a prepreg, and a carbon fiber reinforced composite material. The present invention provides carbon fibers coated with a sizing agent that includes an aliphatic epoxy compound (A) and at least an aromatic epoxy compound (B1) as an aromatic compound (B). The carbon fibers have an (a)/(b) ratio of 0.50 to 0.90 where (a) is the height (cps) of a component at a binding energy (284.6 eV) assigned to CHx, C-C, and C=C and (b) is the height (cps) of a component at a binding energy (286.1 eV) assigned to C-O in a C 1s core spectrum of the surface of the sizing agent analyzed by X-ray photoelectron spectroscopy using AlK± 1,2 as the X-ray source at a photoelectron takeoff angle of 15°.
机译:提供了一种上浆剂涂覆的碳纤维,其在碳纤维与基体树脂之间实现优异的粘合性,并得到一种预浸料,该预浸料在长期保存后具有优异的复合物理性能稳定性,并且具有优异的高阶加工性。涂有碳纤维的材料,预浸料和碳纤维增强的复合材料。本发明提供了涂覆有上浆剂的碳纤维,所述上浆剂包括脂族环氧化合物(A)和至少一种芳族环氧化合物(B1)作为芳族化合物(B)。碳纤维的(a)/(b)比为0.50至0.90,其中(a)是组分的结合能(284.6 eV)下的高度(cps)分配给CHx,CC和C = C,并且( b)是在上浆剂表面的C 1s核心光谱中以AlK±1,2作为元素的X射线光电子能谱分析的,分配给CO的结合能(286.1 eV)时组分的高度(cps)。 X射线源的光电子起飞角为15°。

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