MOLECULAR DESIGN AND DEVELOPMENT OF ADVANCED, HIGH PERFORMANCE AND RELIABLE GREEN EXPLOSIVES.

摘要

The invention related to the design and development of polytriazole based dendriticnitrate esters. The molecular framework of the motifs was engineered to ensure their promising energetic performance. The presence of triazole as a core of this framework not only provided the thermal stability and low impact sensitivity but also responsible for their nitrogen richness. Simultaneously, decoration of triazole with polynitrate esters played an appreciable role in enhancement of their oxygen balance, density and detonation performances. In summary, the energetic motifs with dendritic molecular architecture and enhanced performance were synthesized by adopting a microwave assisted user as well as eco-friendly synthetic protocol.