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Pd/C catalyst, method for preparation Pd/C catalyst, its use in the reaction electroreduction of oxygen in fuel cells on formic acid and such a fuel cell

机译:Pd / C催化剂,Pd / C催化剂的制备方法,其在燃料电池上甲酸与该燃料电池的反应电还原中的用途

摘要

the subject invention is catalyst pd / c, especially for elektroredukcji oxygen cathode of fuel cells for formic acid, containing palladium deposited on the medium coal, whose specific activity on the cathode cell to formic acid is higher than the hitherto used activity him more expensive catalyst based on platinum, characterized by that,in this catalyst, a palladium metal activated in response elektroredukcji oxygen exists in the form of nanoparticles with sizes ranging from 2 nm to 15 nm, and the concentration of weight in the range of 10% by weight. to 60 wt%., and is deposited on the medium coal previously under optimised pre-treatment (funkcjonalizacji), advantageously concentrated nitric acid at a temperature 80u00b0c by 4 - 6 hours. in addition, the invention includes a method for pd / c catalyst and its application to the reduction of oxygen in the cell for formic acid, as well as a fuel cell.
机译:本发明的催化剂是钯/碳催化剂,特别是用于甲酸的燃料电池的电子阴极,其包含沉积在中等煤上的钯,其对甲酸的比活度比迄今使用的活度高,因此较昂贵一种基于铂的催化剂,其特征在于,在该催化剂中,响应电氧活化的钯金属以纳米颗粒的形式存在,其尺寸为2nm至15nm,重量浓度为10%(重量)。 。到60wt%,并预先在优化的预处理(funkcjonalizacji)下沉积在中等煤上,有利的是在80℃的温度下浓缩硝酸至4-6小时。另外,本发明包括用于钯/碳催化剂的方法及其在还原甲酸电池和燃料电池中的氧气中的应用。

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