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Use of ionic liquids to implement a procedure for the preparation of biodiesel

机译:使用离子液体实施生物柴油的制备程序

摘要

Use of a combination of - at least one ionic liquid that is lipophilic, and immiscible with water, and - at least one enzyme, in which the lipophilic ionic liquid is constituted by a lipophilic cation and a hydrophobic anion, said cation being constituted by a cationic head and said anion being constituted by an anionic head and in which said cationic head and / or anionic head are replaced by one or more secondary carbon chains that can be similar or different from each other, and in which the chain Secondary carbon in the cationic head and / or the anionic head are straight or branched carbon chains, saturated or unsaturated, assuming that at least one of the secondary chains comprises at least 10 carbon atoms, in which the enzyme is a lipase or an esterase, for the implementation of an esterification and / or transesterification process of a substrate with at least one alcohol, said substrate consisting of oils, fats, fatty acids or a mixture thereof, in which said ionic liquid, said substrate and said alcohol form a single homogeneous liquid phase at the temperature at which the esterification and / or transesterification process is carried out.
机译:-以下的组合的使用:-至少一种亲脂性且与水不混溶的离子液体,和-至少一种酶,其中所述亲脂性离子液体由亲脂性阳离子和疏水性阴离子构成,所述阳离子由阳离子头和所述阴离子由阴离子头构成,并且其中所述阳离子头和/或阴离子头被一个或多个彼此相似或不同的仲碳链所取代,并且其中阳离子头和/或阴离子头是饱和或不饱和的直链或支链碳链,假定至少一个仲链包含至少10个碳原子,其中酶是脂肪酶或酯酶,用于实现底物与至少一种醇的酯化和/或酯交换过程,所述底物由油,脂肪,脂肪酸或其混合物组成,其中所述离子液体d。底物和所述醇在进行酯化和/或酯交换过程的温度下形成单一的均相液相。

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