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SELECTIVE HYDROGENATION CATALYST FOR PRODUCING BIODIESEL AND PREPARATION METHOD AND APPLICATION THEREFOR

机译:一种生产生物柴油的选择性加氢催化剂及其制备方法和应用

摘要

A selective hydrogenation catalyst for producing biodiesel and a preparation method and an application therefor. The selective hydrogenation catalyst comprises a carrier and a main metal active component, the main metal active component being loaded onto the carrier; the weight percentage of the catalyst product occupied by the main metal active component is 5-30%, the main metal active component being one or a combination of more than one oxide containing Co, Mo, Ni, or W, and the carrier being composed of 1-8% molecular sieves, 25-65% amorphous silicon aluminium, 30-65% aluminium oxide, and 2-10% graphene adjuvant calculated by weight percentage of the raw ingredient. The method for preparing the catalyst comprises immersing the carrier in a metal salt solution containing Co, Mo, Ni, and/or W for 4-20 h to obtain an immersed carrier; and, after freeze-drying, calcining the immersed carrier to obtain the selective hydrogenation catalyst. Under the same load, the carrier has a larger active surface area and has more active sites, reducing reaction temperature and improving hydrogenation performance.
机译:用于生产生物柴油的选择性加氢催化剂及其制备方法和应用。选择性加氢催化剂包括载体和主要金属活性组分,该主要金属活性组分负载在载体上。主要金属活性成分所占催化剂产物的重量百分比为5-30%,主要金属活性成分为含Co,Mo,Ni或W的氧化物中的一种或两种以上的组合,并组成载体按原料的重量百分数计算,可得到1-8%的分子筛,25-65%的非晶硅铝,30-65%的氧化铝和2-10%的石墨烯助剂。制备催化剂的方法包括将载体浸入含有Co,Mo,Ni和/或W的金属盐溶液中4-20h以获得浸没的载体。冷冻干燥后,将浸渍后的载体煅烧,得到选择性氢化催化剂。在相同负载下,该载体具有较大的活性表面积和更多的活性位点,降低了反应温度并提高了氢化性能。

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