首页> 外国专利> METHOD FOR SYNTHESIZING METAL NANOWIRE METAL NANOWIRE MANUFACTURED BY THE SAME AND TRANSPARENT ELECTRODE AND ORGANIC LIGHT EMITTING DIODE INCLUDING THE CORE-SHELL NANOWIRE

METHOD FOR SYNTHESIZING METAL NANOWIRE METAL NANOWIRE MANUFACTURED BY THE SAME AND TRANSPARENT ELECTRODE AND ORGANIC LIGHT EMITTING DIODE INCLUDING THE CORE-SHELL NANOWIRE

机译:相同的,透明的电极和包括壳型纳米线的有机发光二极管制造的金属纳米线的合成方法

摘要

The present invention relates to a nanowire including at least one wire portion, wherein an angle? Between an arbitrary n-th wire portion and an n + 1-th wire portion connected by the n-th wire portion and the n-th bend portion is 0 alpha 180 DEG, The present invention also relates to a nanowire including at least two wire portions, wherein the nanowire includes an arbitrary n-th wire portion and an n + 1-th wire portion connected to the n-th nanowire, The diameter of one wire portion provides different metal nanowires, The present invention also relates to nanowire cores; And a metal compound shell formed on the nanowire core, wherein the core-shell nanowire comprises: The present invention also provides a process for preparing a reaction mixture, which comprises mixing a metal salt, a reducing solvent for reducing the metal salt to a metal, a capping agent for growing the metal in a wire form, and a catalyst; And reacting the reaction mixture in a reaction vessel at a reaction temperature of 1 to 5 atm to form at least two wire portions and having at least one bent portion, The present invention also provides a process for preparing a reaction mixture, which comprises mixing a metal salt, a reducing solvent for reducing the metal salt to a metal, a capping agent for growing the metal in a wire form, and a catalyst; And reacting the reaction mixture in a reaction vessel at a reaction temperature of 1 to 5 atm to produce nanowires having at least one or more diameters of different diameters, The present invention also provides a method of manufacturing a nanowire core comprising: preparing a nanowire core on a substrate; Contacting a nanoparticle core with a precursor solution to form a metal compound shell; And forming a metal compound shell on the nanowire core by supplying growth energy to the core-shell nanowire, The present invention also relates to a conductive layer comprising a metal nanowire; And a light transmitting electrode layer formed on the conductive layer, wherein the metal nanowire includes at least one wire portion, the nanowire including an arbitrary n-th wire portion, an n-th wire portion, and an n-th bent portion And the angle? Between mutually connected n + 1-th wire portions satisfies 0 ? 180, The present invention also relates to a conductive layer comprising a metal nanowire; And a light transmitting electrode layer formed on the conductor layer, wherein the metal nanowire is nanowire including at least two wire portions, the nanowire including an arbitrary n-th wire portion and an n + 1 Wherein the diameter of the n-th wire and the diameter of the n + 1-th wire are different metal nanowires, The present invention also relates to a conductive layer comprising core-shell nanowires; And a light-transmitting electrode layer formed on the conductor layer, wherein the core-shell nanowire comprises: a nanowire core; And a metal compound shell formed on the nanowire core, (Or core-shell) nanowire having excellent electrical conductivity and suitable transmittance and haze value, a method for producing the same, a transparent electrode containing the same, and an organic light emitting device.
机译:纳米线技术领域本发明涉及一种纳米线,其包括至少一个线部分,其中角度α为0。本发明还涉及一种纳米线,该纳米线包括:任意的第n个金属丝部分和由第n个金属丝部分连接的第n + 1个金属丝部分与第n个弯曲部分之间的0 <α<180°。至少两个线部分,其中所述纳米线包括任意的第n个线部分和连接至第n个纳米线的第n + 1个线部分,一个线部分的直径提供不同的金属纳米线,本发明还涉及纳米线核心;以及在纳米线核上形成的金属化合物壳,其中,核-壳纳米线包括:本发明还提供了一种制备反应混合物的方法,该方法包括将金属盐,还原剂混合以将金属盐还原为金属。 ,用于以线状生长金属的封端剂和催化剂;使反应混合物在反应容器中在1至5个大气压的反应温度下反应以形成至少两个线部分并具有至少一个弯曲部分。本发明还提供了一种制备反应混合物的方法,该方法包括将金属盐,用于将金属盐还原为金属的还原溶剂,用于使金属以线状生长的封端剂和催化剂;并使反应混合物在反应容器中在1至5atm的反应温度下反应以产生具有至少一个或多个不同直径的直径的纳米线。本发明还提供一种制造纳米线芯的方法,该方法包括:制备纳米线芯在基板上;使纳米颗粒核与前体溶液接触以形成金属化合物壳;并且通过向芯-壳纳米线供应生长能量在纳米线芯上形成金属化合物壳。以及在导电层上形成的透光电极层,其中金属纳米线包括至少一个线部分,该纳米线包括任意的第n线部分,第n线部分和第n弯曲部分,并且角度?在相互连接的第n + 1个导线部分之间满足0≤θ≤180。本发明还涉及包括金属纳米线的导电层。以及形成在所述导体层上的透光电极层,其中所述金属纳米线是包括至少两个线部分的纳米线,所述纳米线包括任意的第n线部分和n + 1,其中所述第n线的直径和第n + 1条线的直径是不同的金属纳米线。本发明还涉及包含核-壳纳米线的导电层。以及形成在所述导体层上的透光电极层,其中所述核-壳纳米线包括:纳米线核;和以及形成在纳米线核上的金属化合物壳,具有优异的导电性和合适的透射率和雾度值的(或核-壳)纳米线,其制备方法,包含该化合物的透明电极以及有机发光装置。

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