首页> 外国专利> HETEROGENEOUS BRONSTED ACID CATALYSTS AND ESTERIFICATION OF FATTY ACID WITH POLYHYDRIC ALCOHOL USING THE SAME

HETEROGENEOUS BRONSTED ACID CATALYSTS AND ESTERIFICATION OF FATTY ACID WITH POLYHYDRIC ALCOHOL USING THE SAME

机译:异质布朗斯酸催化剂和脂肪醇与多元醇的酯化反应

摘要

The present invention relates to a carbon-based heterogeneous Bronsted acid catalyst and a method for esterifying a fatty acid by using a polyhydric alcohol using the same, wherein the method comprises: a powder preparation step of pulverizing a woody biomass to produce a powder; A carbon body manufacturing step for producing a carbon body by incompletely carbonizing the powder by heat treatment; A step of introducing a sulfonic acid group by introducing a sulfonic acid group by treating sulfuric acid substituted with an electron withdrawing group to the carbon body to produce a heterogeneous Bronsted acid catalyst having a sulfonic acid group introduced therein; And performing an esterification reaction of the polyhydric alcohol and the fatty acid under the solventless condition using the acid catalyst. According to the present invention, a high esterification yield can be obtained by applying a carbon-based heterogeneous Bronsted acid catalyst having excellent mechanical properties and excellent catalytic activity to the esterification reaction between a polyhydric alcohol and a fatty acid.
机译:本发明涉及一种碳基非均质布朗斯台德酸催化剂和使用该非均质布朗斯台德酸催化剂通过使用多元醇酯化脂肪酸的方法,该方法包括:粉碎木质生物质以制备粉末的粉末制备步骤;碳体制造步骤,通过热处理使粉末不完全碳化来制造碳体。通过将被吸电子基团取代的硫酸处理到碳体上而引入磺酸基,从而生成磺酸基的步骤,从而引入磺酸基。然后,使用酸催化剂在无溶剂条件下进行多元醇与脂肪酸的酯化反应。根据本发明,通过将具有优异的机械性能和优异的催化活性的碳基非均质布朗斯台德酸催化剂应用于多元醇和脂肪酸之间的酯化反应,可以获得高的酯化收率。

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