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METHOD FOR EXTRACTION OF PLATINUM METALS FROM PRODUCT OF ACID DISSOLUTION OF VOLXIDIZED WASTE NUCLEAR FUEL

机译:从固溶核燃料酸溶解产物中提取铂金属的方法

摘要

FIELD: fuel.SUBSTANCE: invention relates to spent nuclear fuel (SNF) processing. Method of platinum group metals extracting from product of voloxidized SNF acid dissolving involves, that obtained after voloxidiation SNF is dissolved in nitric acid in the range of temperatures of 83–86 °C for 4–5 hours to obtain residual nitric acid content in product in range of 1.42–2.3 mol/l,uranium in range of 480–600 g/l, obtained product is thermostated in range of temperatures of 69–80°C for 2–48 hours, adding flocculant and dispersing reaction mixture, performing sediment accumulation in device bottom part by sedimentation deposition in range of temperatures of 35–57 °C for 6–24 hours. Product clarified part is separated by decantation, averaging sedimented deposit in remaining clarified solution amount in device.EFFECT: invention enables to extract into deposit of more 78,7 % of platinoids and separate 98,1 % of suspensions formed during SNF dissolving.15 cl, 2 ex
机译:技术领域本发明涉及乏核燃料(SNF)处理。从溶解于SNF的氧化过氧化产物中提取铂族金属的方法涉及,将溶解于SNF的SNF在83–86°C的温度范围内溶解于硝酸中4至5个小时,以获取残留的硝酸含量。范围为1.42–2.3 mol / l,铀范围为480–600 g / l,将所得产品在69–80°C的温度范围内恒温2–48小时,添加絮凝剂并分散反应混合物,进行沉积物积累在设备底部通过在35–57°C的温度范围内进行6-24小时的沉积来沉积。通过倾析分离出产品澄清的部分,将沉淀的沉淀物在装置中的剩余澄清溶液量中平均。效果:本发明能够提取出更多的78.7%的类铂,并分离出在SNF溶解过程中形成的98.1%的悬浮液。15cl ,2前

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