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Catalytic complexes with carbene ligands, process for their preparation and use in the metathesis reaction

机译:卡宾配体的催化配合物,制备方法及在复分解反应中的应用

摘要

This invention relates to catalyst compounds and the synthesis and applications useful in olefin metathesis reactions. The catalyst compounds of the invention are represented by the formula (I): wherein M is a Group 8 metal; X1 and X2 are anionic ligands; L1 and L2 are neutral two electron donor ligands. The present invention also relates to an easy applicable catalyst synthesis and the application in different olefin metathesis processes, e.g. Reaction Injection Molding (RIM), process to make α-olefins from fatty acid ester, e.g. methyl oleate.
机译:本发明涉及在烯烃复分解反应中有用的催化剂化合物及其合成和应用。本发明的催化剂化合物由式(I)表示:其中M是第8族金属;和X1和X2是阴离子配体; L1和L2是中性的两个电子给体配体。本发明还涉及易于应用的催化剂合成以及其在不同的烯烃复分解过程中的应用,例如烯烃的合成。反应注射成型(RIM),由脂肪酸酯制备α-烯烃的工艺,例如油酸甲酯。

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