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METHOD FOR MANUFACTURING HYBRID IMOGOLITE NANOTUBES

机译:混合杂色纳米管的制造方法

摘要

The present invention relates to a method for manufacturing hybrid imogolite nanotubes, which includes the following steps: (i) dissolving an aluminium precursor in an aqueous solution; (vi) under agitation, adding at least one silicon alkoxide, in which the silicon has hydrolysable substituents and at least one non-hydrolysable substituent, to the aluminium solution obtained at the end of step (i), the molar ratio of Al/Si necessarily being from 1 to 4; (vii) under agitation, adding a base to the aluminosilicate solution obtained at the end of step (ii), until obtaining a hydrolysis ratio of 1 to 3; (viii) maintaining agitation for a duration of at least 15 hours; (ix) heating the solution obtained at the end of step (iv) to a temperature of 50° C. to 150° C. for a duration of 2 to 8 days. The present invention also relates to hybrid imogolite nanotubes that simultaneously include a hydrophilic surface and a hydrophobic surface, and have an outer diameter of 3.3 nm to 3.4 nm, which can be obtained via said method.
机译:本发明涉及一种用于制造杂配伊莫石纳米管的方法,该方法包括以下步骤:(i)将铝前体溶解在水溶液中; (vi)在搅拌下,向步骤(i)结束时得到的铝溶液中加入至少一种烷氧基硅,其中硅具有可水解的取代基和至少一个不可水解的取代基必须是1到4; (vii)在搅拌下,向步骤(ii)结束时获得的硅铝酸盐溶液中加入碱,直至水解比为1至3; (viii)保持搅拌至少15小时; (ix)将步骤(iv)结束时获得的溶液加热至50℃至150℃的温度持续2至8天。本发明还涉及同时包括亲水性表面和疏水性表面并且具有3.3nm至3.4nm的外径的杂化伊戈石纳米管,其可以通过所述方法获得。

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