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QUANTIFICATION METHOD FOR DETERMINING THE CONCENTRATION OF HYDROGEN PHOSPHATE IONS IN WATER

机译:测定水中磷酸氢根离子浓度的定量方法

摘要

The present invention addresses the problem of providing an inexpensive ion sensor catalyst capable of detecting hydrogen phosphate ions in water and determining hydrogen phosphate ion concentration on the basis of oxidation current density for the ions, along with an ion sensor and a quantification method, the ion sensor catalyst being characterized by providing higher detection sensitivity than conventional ion sensor catalysts, being capable of maintaining high detection sensitivity over a wide range of hydrogen phosphate ion concentration, achieving a proportional relationship between concentration and oxidation current density, so that the concentration can be determined with accuracy regardless of the concentration range, and allowing oxidation current to reach a steady-state value in a short time, so that time to determine current density is short, resulting in shortened time to quantify hydrogen phosphate ions, and stable response to hydrogen phosphate ion oxidation can be made repeatedly . To solve the problem, the ion sensor catalyst of the present invention for electrochemically oxidizing hydrogen phosphate ions in water includes a mixed oxide of ruthenium oxide and tantalum oxide.
机译:本发明解决了以下问题:提供一种廉价的离子传感器催化剂,其能够检测水中的磷酸氢根离子并基于离子的氧化电流密度确定磷酸氢根离子浓度,以及离子传感器和定量方法,离子。传感器催化剂的特征在于,与以往的离子传感器催化剂相比,具有更高的检测灵敏度,能够在磷酸氢根离子浓度的宽范围内维持高的检测灵敏度,能够实现浓度与氧化电流密度的比例关系,从而能够确定浓度。无论浓度范围如何,其精度都很高,并且允许氧化电流在短时间内达到稳态值,从而缩短了确定电流密度的时间,从而缩短了量化磷酸氢根离子的时间,并且对磷酸氢根具有稳定的响应可以进行离子氧化反复地。为了解决该问题,用于电化学氧化水中的磷酸氢根离子的本发明的离子传感器催化剂包括氧化钌和氧化钽的混合氧化物。

著录项

  • 公开/公告号EP3106866B1

    专利类型

  • 公开/公告日2018-06-13

    原文格式PDF

  • 申请/专利权人 THE DOSHISHA;

    申请/专利号EP20150749488

  • 发明设计人 MORIMITSU MASATSUGU;

    申请日2015-02-04

  • 分类号G01N27/416;G01N27/30;G01N27/407;G01N27/333;G01N33/18;

  • 国家 EP

  • 入库时间 2022-08-21 13:18:42

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