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Scandia-stabilized zirconia electrolyte for solid oxide fuel cells with improved reducing atmosphere stability

机译:用于固体氧化物燃料电池的斯堪的纳稳定氧化锆电解质,具有改善的还原气氛稳定性

摘要

Disclosed is a scandia-stabilized zirconia electrolyte for a solid oxide fuel cell, which is configured such that at least one oxide selected from among gadolinium oxide (Gd2O3) and samarium oxide (Sm2O3) is co-doped with ytterbium oxide (Yb2O3) to thus improve stability in a reducing atmosphere. The scandia-stabilized zirconia electrolyte of the invention can be stabilized into a cubic crystal structure at room temperature while retaining the inherently high oxygen ionic conductivity of a scandia-stabilized zirconia electrolyte (11ScSZ), and can also ensure stability in a reducing atmosphere by solving the problem with a conventional ceria (CeO2)-doped scandia-stabilized zirconia in which the ionic conductivity continuously deteriorates in a reducing atmosphere.
机译:公开了一种用于固体氧化物燃料电池的氧化scan稳定的氧化锆电解质,其构造为使得从氧化oxide(Gd2O3)和氧化mar(Sm2O3)中选择的至少一种氧化物与氧化(Yb2O3)共掺杂,从而提高还原性气氛中的稳定性。本发明的scan稳定氧化锆电解质可以在室温下稳定为立方晶结构,同时保持a稳定氧化锆电解质(11ScSZ)固有的高氧离子电导率,并且还可以通过溶解来确保在还原气氛中的稳定性。这是常规的二氧化铈(CeO 2)掺杂的dia稳定氧化锆的问题,其中在还原性气氛中离子电导率连续降低。

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