首页> 外国专利> MESOPOROUS AND MACROPOROUS NICKEL-BASED CATALYST HAVING A MEDIAN MACROPORE DIAMETER OF BETWEEN 50 NM AND 200 NM AND ITS USE WITH REGARD TO HYDROGENATION

MESOPOROUS AND MACROPOROUS NICKEL-BASED CATALYST HAVING A MEDIAN MACROPORE DIAMETER OF BETWEEN 50 NM AND 200 NM AND ITS USE WITH REGARD TO HYDROGENATION

机译:具有约50 NM和200 NM之间的中值大孔直径的介孔和大孔镍基催化剂,以及与加氢有关的用途

摘要

Disclosed are a supported catalyst, its method of preparation and use in hydrogenation methods, which catalyst contains an oxide substrate that is for the most part calcined aluminum and an active phase that contains nickel, with the nickel content between 5 and 65% by weight in relation to the total mass of the catalyst, with the active phase not containing a metal from group VIB, the nickel particles having a diameter that is less than or equal to 20 nm, the catalyst having a median mesopore diameter of between 14 nm and 30 nm, a median macropore diameter of between 50 and 200 nm, a mesopore volume that is measured by mercury porosimetry that is greater than or equal to 0.40 mL/g, and a total pore volume that is measured by mercury porosimetry that is greater than or equal to 0.42 mL/g.
机译:公开了一种负载型催化剂,其制备方法和用于氢化方法中,该催化剂包含主要用于煅烧的铝的氧化物基质和包含镍的活性相,其中镍含量为5-65重量%。相对于催化剂的总质量,活性相不含VIB族金属,镍颗粒的直径小于或等于20 nm,催化剂的中孔直径中位数为14 nm至30 ,中值大孔直径在50到200 nm之间,通过汞孔隙率法测量的中孔体积大于或等于0.40 mL / g,通过汞孔隙率法测量的总孔体积大于或等于0.40 mL / g等于0.42 mL / g。

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