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ORGANIC MAGNESIUM PHOSPHIDE AND METHOD FOR PRODUCING SAME, ORGANIC MAGNESIUM PHOSPHIDE COMPLEX AND METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING ORGANIC PHOSPHORUS-CONTAINING COMPOUND USING SAID PHOSPHIDE
ORGANIC MAGNESIUM PHOSPHIDE AND METHOD FOR PRODUCING SAME, ORGANIC MAGNESIUM PHOSPHIDE COMPLEX AND METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING ORGANIC PHOSPHORUS-CONTAINING COMPOUND USING SAID PHOSPHIDE
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机译:有机磷酸镁及其制备方法,有机磷酸镁络合物,制备方法以及使用所述磷酸酯制备含磷化合物的方法
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摘要
The present invention addresses the problem of providing: a novel organic magnesium phosphide characterized by having a phosphorus-magnesium bond and a method for producing the organic magnesium phosphide; and a novel organic magnesium phosphide complex and a method for producing the organic magnesium phosphide complex. The present invention also addresses the problem of providing a novel method for producing an organic phosphorus-containing compound using the organic magnesium phosphide or the organic magnesium phosphide complex. As a solution, an organic magnesium phosphide represented by formula (1) and an organic magnesium phosphide complex represented by formula (9) are provided. Also provided is a method for producing an organic phosphorus-containing compound, characterized by reacting any one of the reagents with an electrophile.(In the formula, R1 and R2 independently represent an aliphatic group, a heteroaliphatic group, an alicyclic group or a heterocyclic group; and X represents a chlorine atom, a bromine atom or a iodine atom.)(In the formula, R3 and R4 independently represent an aliphatic group, a heteroaliphatic group, an aromatic group, an alicyclic group or a heterocyclic group; and X and Y independently represent a chlorine atom, a bromine atom or a iodine atom.)
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