首页> 外国专利> ORGANIC MAGNESIUM PHOSPHIDE AND METHOD FOR PRODUCING SAME, ORGANIC MAGNESIUM PHOSPHIDE COMPLEX AND METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING ORGANIC PHOSPHORUS-CONTAINING COMPOUND USING SAID PHOSPHIDE

ORGANIC MAGNESIUM PHOSPHIDE AND METHOD FOR PRODUCING SAME, ORGANIC MAGNESIUM PHOSPHIDE COMPLEX AND METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING ORGANIC PHOSPHORUS-CONTAINING COMPOUND USING SAID PHOSPHIDE

机译:有机磷酸镁及其制备方法,有机磷酸镁络合物,制备方法以及使用所述磷酸酯制备含磷化合物的方法

摘要

The present invention addresses the problem of providing: a novel organic magnesium phosphide characterized by having a phosphorus-magnesium bond and a method for producing the organic magnesium phosphide; and a novel organic magnesium phosphide complex and a method for producing the organic magnesium phosphide complex. The present invention also addresses the problem of providing a novel method for producing an organic phosphorus-containing compound using the organic magnesium phosphide or the organic magnesium phosphide complex. As a solution, an organic magnesium phosphide represented by formula (1) and an organic magnesium phosphide complex represented by formula (9) are provided. Also provided is a method for producing an organic phosphorus-containing compound, characterized by reacting any one of the reagents with an electrophile.(In the formula, R1 and R2 independently represent an aliphatic group, a heteroaliphatic group, an alicyclic group or a heterocyclic group; and X represents a chlorine atom, a bromine atom or a iodine atom.)(In the formula, R3 and R4 independently represent an aliphatic group, a heteroaliphatic group, an aromatic group, an alicyclic group or a heterocyclic group; and X and Y independently represent a chlorine atom, a bromine atom or a iodine atom.)
机译:本发明解决的问题是提供:一种新颖的以磷-镁键为特征的有机磷化镁及其制备方法;以及新型的有机磷化镁配合物和制备有机磷化镁配合物的方法。本发明还解决了提供使用有机磷化镁或有机磷化镁配合物生产有机含磷化合物的新颖方法的问题。作为溶液,提供由式(1)表示的有机磷化镁和由式(9)表示的有机磷化镁配合物。还提供了一种制备有机含磷化合物的方法,其特征在于使任何一种试剂与亲电试剂反应。(式中,R 1 和R 2 独立地表示脂肪族基,杂脂族基,脂环族基或杂环基; X表示氯原子,溴原子或碘原子。)(式中,R 3 和R 4 分别表示脂肪族基团,杂脂族基团,芳香族基团,脂环族基团或杂环基团; X和Y独立地表示氯原子,溴原子或碘原子)。

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