ORGANIC MAGNESIUM PHOSPHIDE AND METHOD FOR PRODUCING SAME, ORGANIC MAGNESIUM PHOSPHIDE COMPLEX AND METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING ORGANIC PHOSPHORUS-CONTAINING COMPOUND USING SAID PHOSPHIDE

摘要

An object is to provide a new organic magnesium phosphide characterized by phosphorus-magnesium bond, and a manufacturing method thereof, as well as a new organic magnesium phosphide complex and a manufacturing method thereof. Another object is to provide a new manufacturing method of organic phosphorus compound using such organic magnesium phosphide or organic magnesium phosphide complex. As a means for solving the problems, an organic magnesium phosphide expressed by Formula (1) below, an organic magnesium phosphide complex expressed by Formula (9) below, and a manufacturing method of organic phosphorus compound characterized in that any such reagent is reacted with an electrophile, are provided:(In the formula, R¹ and R² are each independently an aliphatic group, heteroaliphatic group, alicyclic group, or heterocyclic group, and X is chlorine, bromine, or iodine.)(In the formula, R³ and R⁴ are each independently an aliphatic group, heteroaliphatic group, aromatic group, alicyclic group, or heterocyclic group, and X and Y are each independently chlorine, bromine, or iodine.)