首页> 外国专利> PALLADIUM OXIDE CATALYST FOR DIRECT FORMIC ACID FUEL CELL AND PREPARATION METHOD THEREFOR

PALLADIUM OXIDE CATALYST FOR DIRECT FORMIC ACID FUEL CELL AND PREPARATION METHOD THEREFOR

机译:直接甲酸燃料电池用氧化钯催化剂及其制备方法

摘要

The present invention discloses a palladium oxide catalyst for a direct formic acid fuel cell and a preparation method therefor. The preparation method is as follows: dissolving palladium chloride into an aqueous solution, and adding sodium citrate or potassium citrate to adjust the pH value of the solution to 9-13; then placing the above solution in a microwave reactor for microwave reaction for 3-30 minutes, while simultaneously performing reflux and magnetic stirring, to obtain a palladium oxide colloidal solution; after the palladium oxide colloid is cooled, adding a commercial carbon powder or carbon nanotubes to collect palladium oxide; and finally, performing suction filtration, and washing, vacuum-drying, and grinding of a filter cake, to obtain a carbon-supported palladium oxide catalyst. The present invention uses water as a solvent and is green and environmentally friendly, and no organic substance is involved in the reaction in the whole process; further, the invention does not add any protective agent with a high molecular weight, so that post-treatment is not required after the preparation of the catalyst, and it features a short reaction time and a reduced energy consumption. The process for preparing the palladium oxide electrocatalyst of the present invention is simple and facilitates mass production.
机译:本发明公开了一种用于直接甲酸燃料电池的氧化钯催化剂及其制备方法。制备方法如下:将氯化钯溶解于水溶液中,加入柠檬酸钠或柠檬酸钾调节溶液的pH值为9-13。然后将上述溶液置于微波反应器中进行微波反应3-30分钟,同时进行回流和磁力搅拌,得到氧化钯胶体溶液。氧化钯胶体冷却后,加入市售碳粉或碳纳米管收集氧化钯。最后,进行抽滤,洗涤,真空干燥,粉碎滤饼,得到碳负载的氧化钯催化剂。本发明以水为溶剂,绿色环保,反应全过程不涉及有机物。此外,本发明不添加任何高分子量的保护剂,因此在制备催化剂后不需要后处理,并且本发明具有反应时间短和能耗降低的特征。本发明的氧化钯电催化剂的制备方法简单,易于大量生产。

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