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METHOD FOR PREPARING LEVOGLUCOSENONE BY CATALYTIC PYROLYSIS OF BIOMASS

机译:生物质的催化热解制备左旋糖皮质激素的方法

摘要

The present invention falls within the field of biomass energy utilization, and in particular relates to a method for preparing levoglucosenone by means of the catalytic pyrolysis of biomass. The present invention uses a biomass-based phosphoric acid-activated active carbon as a catalyst; by subjecting same to mechanical mixing with the biomass, rapid pyrolysis is performed under inert anaerobic conditions at 250-470°C; and the pyrolysis gas is condensed. Then, a liquid product enriched in levoglucosenone can be obtained. In pyrolysis products obtained by means of the biomass-based phosphoric acid-activated active carbon catalyzing the pyrolysis of the biomass, the yield and purity of levoglucosenone are both quite high. In addition, the mixture of the solid coke produced by the pyrolysis and the catalyst can be used as a carbon source for the continuous preparation of active carbon. By means of using the inexpensive and reusable biomass-based phosphoric acid-activated active carbon, the method can effectively lower the production cost and reduce pollution, and is an economical and effective method for preparing levoglucosenone.
机译:本发明属于生物质能利用领域,尤其涉及一种通过生物质的催化热解制备左旋葡糖酮的方法。本发明使用基于生物质的磷酸活化的活性炭作为催化剂。通过将其与生物质进行机械混合,在惰性厌氧条件下于250-470°C进行快速热解。并且热解气体被冷凝。然后,可以得到富含左葡萄糖苷的液体产物。在通过基于生物质的磷酸活化的活性炭催化生物质的热解而获得的热解产物中,左葡萄糖苷的产率和纯度都很高。另外,通过热解产生的固体焦炭和催化剂的混合物可以用作连续制备活性炭的碳源。通过使用廉价且可重复使用的基于生物质的磷酸活化活性炭​​,该方法可以有效降低生产成本,减少污染,是一种经济有效的制备左旋葡糖酮的方法。

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