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A HYDROGEN PEROXIDE ELECTROCHEMICAL SENSOR AND PREPARATION METHOD OF THE SAME

机译:一种过氧化氢电化学传感器及其制备方法

摘要

The present invention relates to a non-enzyme based electrochemical sensor for detecting hydrogen peroxide and a preparation method thereof. The sensor for detecting hydrogen peroxide comprises: a sensor base; a laminated thin film comprising a first metal oxide film and an organic polymer film sequentially stacked on the sensor base; a second metal oxide film stacked on the top of the laminated thin film; and a metal nanoparticle bonded to a nanocomposite thin film of the laminated thin film and the second metal oxide film. The preparation method thereof comprises: (a) a step of providing the sensor base; (b) a step of forming the laminated thin film by sequentially laminating the first metal oxide film and the organic polymer film on the top of the sensor base; (c) a step of forming the nanocomposite thin film of the second metal oxide film on the top of the laminated thin film; and (d) a step of bonding the metal nanoparticles to the nanocomposite thin film of the laminated thin film and the second metal oxide film. The sensor for detecting peroxide according to the present invention is the non-enzyme based sensor and can be prepared in a simple and inexpensive way. By using a metal oxide/polymer nanocomposite thin film in a metal nanoparticles bonded from an electrode of an electrochemical sensor, excellent selectivity, stability, and reproducibility can be realized, and at the same time, a reaction time is short such that rapid detection can be performed.
机译:本发明涉及一种用于检测过氧化氢的基于非酶的电化学传感器及其制备方法。用于检测过氧化氢的传感器包括:传感器底座;层压薄膜,其包括依次堆叠在传感器基底上的第一金属氧化物膜和有机聚合物膜;第二金属氧化物膜堆叠在层压薄膜的顶部上;金属纳米粒子与层叠薄膜和第二金属氧化物薄膜的纳米复合薄膜结合。其制备方法包括:(a)提供传感器底座的步骤; (b)通过依次将第一金属氧化物膜和有机聚合物膜层压在传感器基底的顶部上来形成层压薄膜的步骤; (c)在叠层薄膜的顶部上形成第二金属氧化物膜的纳米复合薄膜的步骤; (d)将金属纳米粒子结合到层叠薄膜和第二金属氧化物薄膜的纳米复合薄膜上的步骤。根据本发明的用于检测过氧化物的传感器是基于非酶的传感器,并且可以以简单且廉价的方式来制备。通过在与电化学传感器的电极结合的金属纳米颗粒中使用金属氧化物/聚合物纳米复合薄膜,可以实现优异的选择性,稳定性和再现性,同时,反应时间短,从而可以快速检测。被执行。

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