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Method for preparing low-odor polyethylene resin composition for plastic closure and Article Produced with the Same

机译:一种用于塑料瓶盖的低气味聚乙烯树脂组合物的制备方法及其制品

摘要

A preparation method of a polyethylene resin composition for a bottle cap of the present invention, as a method of preparing the polyethylene resin composition by copolymerizing ethylene and alpha-olefin in the presence of a solid catalyst including Si, Ti and Mg, comprises performing a degassing process of at least three stages or more on the polyethylene resin composition, wherein the degassing process of the three stages or more has a first stage pressure of 1.2 to 1.5 atmospheric pressure, a second stage pressure of 1.1 to 1.3 atmospheric pressure, and a third stage pressure of 0.9 to 1.1 atmospheric pressure. The polyethylene resin composition has less than 10 ppm of a content of a hydrocarbon having 2 to 10 carbon atoms, exhibits low bad odor characteristics with a smell index of 2.0 or less, and does not generate an unpleasant smell such that the polyethylene resin composition can maintain intrinsic smell characteristics of the beverages when the polyethylene resin composition is applied to the bottle cap for beverages.
机译:作为通过在包括Si,Ti和Mg的固体催化剂存在下使乙烯和α-烯烃共聚来制备聚乙烯树脂组合物的方法,本发明的用于瓶盖的聚乙烯树脂组合物的制备方法包括:对聚乙烯树脂组合物进行至少三阶段以上的脱气处理,其中,三阶段以上的脱气处理的第一阶段压力为1.2〜1.5大气压,第二阶段压力为1.1〜1.3大气压,且第三级压力为0.9至1.1个大气压。聚乙烯树脂组合物具有小于10ppm的具有2至10个碳原子的烃的含量,具有2.0以下的气味指数,显示低的不良气味特性,并且不会产生令人不愉快的气味,使得聚乙烯树脂组合物可以当将聚乙烯树脂组合物应用于饮料的瓶盖时,保持饮料的固有气味特征。

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