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COMPLEX AND PEROVSKITE MATERIAL, AND PEROVSKITE-TYPE SOLAR CELL USING COMPLEX OR PEROVSKITE MATERIAL

机译:复合材料和钙钛矿材料,以及使用复合材料或钙钛矿材料的钙钛矿型太阳能电池

摘要

The complex comprising one or more of the compound represented by general formula: RPb n1 X m1 (wherein R is a cation represented by R 1 NH 3 + (wherein R 1 represents a univalent substituted or unsubstituted hydrocarbon group), or the following formula: (wherein R 2 represents a hydrogen atom, or a univalent substituted or unsubstituted hydrocarbon group); X is the same or different, and each represents a halogen atom; n1 is 0.8 to 1.2; and m1 is 2.8 to 3.2, or the compound represented by general formula: R 2 Pb n2 X m2 wherein R and X are as defined above; n2 is 2.8 to 3.2; and m2 is 7.7 to 8.3; and one or more dimethylformamide molecules is capable of decreasing the stirring time upon dissolution in an organic solvent such as DMSO, as well as decreasing the hysteresis and improving the solar cell characteristics (in particular, photoelectric conversion efficiency) when the complex is applied to a perovskite layer. Further, by using a perovskite material substantially free from lead halide, it is possible to improve the power conversion efficiency (PCE) and the internal quantum efficiency (IQE).
机译:该配合物包含一种或多种由通式RPb n1 X m1(其中R是由R 1 NH 3 +表示的阳离子(其中R 1代表一价取代或未取代的烃基))表示的化合物,或下式:(其中R 2代表氢原子,或一价取代或未取代的烃基); X相同或不同,分别表示卤原子。 n1为0.8到1.2; m1为2.8〜3.2,或通式为R 2 Pb n2 X m2的化合物,其中,R和X与上述相同。 n2为2.8至3.2; m2为7.7至8.3;一个或多个二甲基甲酰胺分子溶解在有机溶剂(如DMSO)中时,能够减少搅拌时间,并能减少磁滞现象并改善将太阳能电池的复合物应用于太阳能电池的特性(特别是光电转换效率)。钙钛矿层。此外,通过使用基本不含卤化铅的钙钛矿材料,可以提高功率转换效率(PCE)和内部量子效率(IQE)。

著录项

  • 公开/公告号EP3392256A4

    专利类型

  • 公开/公告日2019-07-03

    原文格式PDF

  • 申请/专利权人 KYOTO UNIVERSITY;

    申请/专利号EP20160875766

  • 发明设计人 WAKAMIYA ATSUSHI;HIROSE YUMI;SHIMAZAKI AI;

    申请日2016-12-16

  • 分类号C07F7/24;H01L51/44;

  • 国家 EP

  • 入库时间 2022-08-21 12:30:10

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