A redox flow battery includes a battery cell to which a positive electrolyte and a negative electrolyte are supplied, and an electrical quantity measurement system configured to measure a quantity of electricity when a predetermined amount of electrolyte is discharged, for at least one of the positive electrolyte and the negative electrolyte. The electrical quantity measurement system includes an electrolytic cell having a working electrode to which one of the positive electrolyte and the negative electrolyte, in which the quantity of electricity is to be measured, is supplied, and a counter electrode to which the other electrolyte, which is not to be measured, is supplied; a standard electrode disposed, outside the electrolytic cell, so as to be in contact with the one electrolyte to be measured; and a measurement device configured to apply, to the electrolytic cell, a voltage that is set on the basis of a potential of the standard electrode and capable of performing total electrolysis of the one electrolyte contained in the working electrode and measure the quantity of electricity of the one electrolyte.
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