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Novel mesogenic silicon compound (co) polymer and thermoplastic elastomer

机译:新型介晶硅化合物(共)聚合物和热塑性弹性体

摘要

A thermoplastic elastomer composed of a mesogen / silicon compound (co) polymer represented by the following formula (1) and having a number average molecular weight of 1,000 to 500,000 has transparency and rubber physical properties (rubber elasticity), Since it can be thermally reversibly (repetitively) molded, it can be suitably used for potting materials and various sealing materials. [Ar is a mesogenic group selected from the structure represented by the following formula. a represents a positive number of 0.5 to 1, and b represents a number of 0 to 0.5 (where a and b represent the ratio of the number of each repeating unit to the total of all repeating units in the molecule, respectively. A + b = 1). R1 is a monovalent hydrocarbon group not containing an aliphatic unsaturated bond having 1 to 8 carbon atoms, R2 is a hydrogen atom, -Si (CH3) 3, -Si (CH3) 2 (OH), -Si (CH3) 2 (CH = CH2) or -Si (CH3) 2 (CH2-CH = CH2). ]
机译:由下式(1)表示的液晶元/硅化合物(共)聚合物组成的热塑性弹性体具有数均分子量为1,000至500,000的透明性和橡胶物理性质(橡胶弹性),因此可以热可逆地进行。 (重复地)模制,它可以适合用于灌封材料和各种密封材料。 [Ar是选自下式表示的结构的介晶基团。 a表示0.5到1的正数,b表示0到0.5的数(其中a和b分别表示分子中每个重复单元的数量与所有重复单元的总数之比。A + b = 1)。 R1是不包含具有1至8个碳原子的脂族不饱和键的一价烃基,R2是氢原子,-Si(CH3)3,-Si(CH3)2(OH),-Si(CH3)2(CH) = CH2)或-Si(CH3)2(CH2-CH = CH2)。 ]

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