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Mixed metal double salt ionic liquids with tunable acidity

机译:酸度可调的混合金属双盐离子液体

摘要

Disclosed are double salt ionic liquids that include at least one organic cation and at least two metal halide anions. Methods of making the double salt ionic liquids can include combining two or more metal halide containing salts, wherein the metal halide containing salts include at least one organic cation and at least two metal halide anions. The reaction between the two or more salts at any ratio allows fine tuning, rate of dissolution, solubility, and bioavailability of the double salt ionic liquids. The ionic liquids disclosed herein can be used as a catalyst for catalyzing a chemical reaction. The chemical reaction can be an acid catalyzed chemical reaction such as a Lewis acid catalyzed reaction, a Beckmann rearrangement reaction, a Meyer-Schuster rearrangement reaction, a heterocyclic synthesis, a reaction for biodiesel production, a mercury-catalyzed type reaction, or a hydrogen-fluoride catalyzed type reaction.
机译:公开了包含至少一种有机阳离子和至少两种金属卤化物阴离子的双盐离子液体。制备复盐离子液体的方法可包括合并两种或更多种含金属卤化物的盐,其中所述含金属卤化物的盐包括至少一种有机阳离子和至少两种金属卤化物阴离子。两种或多种盐之间以任何比例进行的反应可实现复盐离子液体的微调,溶解速率,溶解度和生物利用度。本文公开的离子液体可以用作用于催化化学反应的催化剂。化学反应可以是酸催化的化学反应,例如路易斯酸催化反应,贝克曼重排反应,迈耶-舒斯特重排反应,杂环合成,用于生物柴油生产的反应,汞催化型反应或氢。 -氟化物催化型反应。

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