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Production method for ion exchange membrane for alkali chloride electrolysis, and production method for alkali chloride electrolysis apparatus

机译:碱金属氯化物电解用离子交换膜的制造方法以及碱金属氯化物电解装置的制造方法

摘要

To provide a method capable of efficiently producing an ion exchange membrane for alkali chloride electrolysis which has high current efficiency, little variation in current efficiency and high alkaline resistance. This is a method for producing an ion exchange membrane 1 having a layer (C) 12 containing a fluorinated polymer (A) having carboxylic acid type functional groups, by immersing an ion exchange membrane precursor film having a precursor layer (C′) containing a fluorinated polymer (A′) having groups convertible to carboxylic acid type functional groups, in an aqueous alkaline solution comprising an alkali metal hydroxide, a water-soluble organic solvent and water, wherein the proportion of structural units having carboxylic acid type functional groups in the fluorinated polymer (A) is from 13.0 to 14.50 mol %; in the layer (C) 12, the value of resistivity is from 4.0×103 to 25.0×103 Ω·cm, and the variation in resistivity is at most 4.0×103 Ω·cm, and the concentration of the water-soluble organic solvent is from 1 to 60 mass % in the alkaline aqueous solution.
机译:本发明提供一种能够有效地制造电流效率高,电流效率的变化少且耐碱性高的用于碱金属氯化物电解的离子交换膜的方法。该方法是通过浸渍离子来制造具有层(C) 12 的离子交换膜 1 的方法,所述层(C) 12 包含具有羧酸型官能团的氟化聚合物(A)。交换膜前体膜,在含有碱金属氢氧化物,水溶性有机物的碱性水溶液中,具有含有含氟聚合物(A′)的前体层(C′),该含氟聚合物具有可转化为羧酸型官能团的基团。溶剂和水,其中,含氟聚合物(A)中的具有羧酸类官能团的结构单元的比例为13.0〜14.50mol%。在(C) 12 层中,电阻率的值从4.0×10 3 到25.0×10 3 Ω·cm,电阻率变化最大为4.0×10 3 Ω·cm,碱性水溶液中的水溶性有机溶剂的浓度为1〜60质量%。

著录项

  • 公开/公告号US10385465B2

    专利类型

  • 公开/公告日2019-08-20

    原文格式PDF

  • 申请/专利权人 AGC INC.;

    申请/专利号US201815908999

  • 申请日2018-03-01

  • 分类号C25B1/46;C08J5/22;C25B13/08;C08F214/26;C25B9/18;C25B9/08;

  • 国家 US

  • 入库时间 2022-08-21 12:16:01

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