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Production method for ion exchange membrane for alkali chloride electrolysis, and production method for alkali chloride electrolysis apparatus

机译:碱金属氯化物电解用离子交换膜的制造方法以及碱金属氯化物电解装置的制造方法

摘要

To provide a method whereby it is possible to efficiently produce an ion exchange membrane for alkali chloride electrolysis, which has high current efficiency and high alkali resistance at the time of electrolyzing an alkali chloride. This is a method for producing an ion exchange membrane 1 for alkali chloride electrolysis, having a layer (C) 12 containing a fluorinated polymer (A) having carboxylic acid type functional groups, by immersing an ion exchange membrane precursor film having a precursor layer (C′) containing a fluorinated polymer (A′) having groups convertible to carboxylic acid type functional groups, in an aqueous alkaline solution comprising an alkali metal hydroxide, a water-soluble organic solvent and water, and subjecting the groups convertible to carboxylic acid type functional groups to hydrolysis treatment to convert them to carboxylic acid type functional groups, wherein the concentration of the water-soluble organic solvent is from 1 to 60 mass % in the alkaline aqueous solution (100 mass %); the proportion of structural units having carboxylic acid type functional groups in the fluorinated polymer (A) is from 14.00 to 14.50 mol %; and the resistivity in the layer (C) 12 is from 3.0×103 to 25.0×103 Ω·cm.
机译:本发明提供一种方法,可以有效地制造用于碱金属氯化物电解的离子交换膜,该离子交换膜在电解碱金属氯化物时具有高电流效率和高碱抗性。这是一种制备用于碱金属氯化物电解的离子交换膜 1 的方法,该膜具有(C) 12 层,该层包含具有羧酸型官能团的氟化聚合物(A)通过将具有前体层(C')的离子交换膜前体膜浸入包含碱金属氢氧化物的碱性水溶液中,所述前体层(C')包含具有可转变为羧酸型官能团的基团的氟化聚合物(A')有机溶剂和水,然后将可转化为羧酸型官能团的基团进行水解处理以将其转化为羧酸型官能团,其中在碱性水溶液中水溶性有机溶剂的浓度为1至60质量%溶液(100质量%);含氟聚合物(A)中具有羧酸类官能团的结构单元的比例为14.00〜14.50mol%。 (C) 12 层的电阻率为3.0×10 3 至25.0×10 3 Ω·cm。

著录项

  • 公开/公告号US10703872B2

    专利类型

  • 公开/公告日2020-07-07

    原文格式PDF

  • 申请/专利权人 AGC INC.;

    申请/专利号US201815909013

  • 申请日2018-03-01

  • 分类号C08J5/22;C25B13/08;C25B1/46;C25B9/08;C25B1/34;

  • 国家 US

  • 入库时间 2022-08-21 11:29:47

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