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Production method for ion exchange membrane for alkali chloride electrolysis, and production method for alkali chloride electrolysis apparatus
Production method for ion exchange membrane for alkali chloride electrolysis, and production method for alkali chloride electrolysis apparatus
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机译:碱金属氯化物电解用离子交换膜的制造方法以及碱金属氯化物电解装置的制造方法
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摘要
To provide a method whereby it is possible to efficiently produce an ion exchange membrane for alkali chloride electrolysis, which has high current efficiency and high alkali resistance at the time of electrolyzing an alkali chloride. This is a method for producing an ion exchange membrane 1 for alkali chloride electrolysis, having a layer (C) 12 containing a fluorinated polymer (A) having carboxylic acid type functional groups, by immersing an ion exchange membrane precursor film having a precursor layer (C′) containing a fluorinated polymer (A′) having groups convertible to carboxylic acid type functional groups, in an aqueous alkaline solution comprising an alkali metal hydroxide, a water-soluble organic solvent and water, and subjecting the groups convertible to carboxylic acid type functional groups to hydrolysis treatment to convert them to carboxylic acid type functional groups, wherein the concentration of the water-soluble organic solvent is from 1 to 60 mass % in the alkaline aqueous solution (100 mass %); the proportion of structural units having carboxylic acid type functional groups in the fluorinated polymer (A) is from 14.00 to 14.50 mol %; and the resistivity in the layer (C) 12 is from 3.0×103 to 25.0×103 Ω·cm.
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