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Thermoelectric conversion material comprising a full-Heusler alloy and method for manufacturing the same by alloying and successively heating a raw material
Thermoelectric conversion material comprising a full-Heusler alloy and method for manufacturing the same by alloying and successively heating a raw material
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机译:包含全赫斯勒合金的热电转换材料及其通过将原材料合金化并连续加热来制造该材料的方法
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摘要
The present invention provides a metal-based thermoelectric conversion material having a high figure-of-merit ZT, the thermoelectric conversion material being a p-type or n-type full-Heusler alloy, having a composition of an Fe2TiA type (wherein A is Si and/or Sn), and including crystal grains having an average grain diameter of 30-500 nm. In particular, in the case where the composition of an Fe2TiA type is represented by the empirical formula Fe2+σTi1+yA1+z, the values of σ, y, and z in an Fe—Ti-A ternary alloy phase diagram lie within the range α surrounded by the points (50, 37, 13), (45, 30, 25), (39.5, 25, 35.5), (50, 14, 36), (54, 21, 25), and (55.5, 25, 19.5) in terms of (Fe, Ti, A) in at %.
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