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Cathode material for Li-ion battery, method for preparing the same and Li-ion battery containing the same

机译:用于锂离子电池的正极材料,其制备方法以及包含该正极材料的锂离子电池

摘要

The present invention relates to the field of the Li-ion battery and, particularly, relates to a cathode material for the Li-ion battery, a method for preparing the same and a Li-ion battery containing the same. A surface of the cathode material of spinel type lithium-manganese-nickel-containing composite oxide of the present invention is coated with a complex coating layer composed of a first coating layer containing Li7La3Zr2O12 and a second coating layer containing LiNbO3. The method includes: firstly coating the first coating layer containing Li7La3Zr2O12 on the surface of spinel type lithium-manganese-nickel-containing composite oxide in a solid phase method; and then coating the second coating layer containing LiNbO3 in a hydro-thermal method. The cathode material of the present invention improves cycle stability and rate performance of spinel type lithium-manganese-nickel-containing composite oxide, and meanwhile reduces dissolution and erosion effect of the electrolyte on the cathode material during charging or discharging.
机译:锂离子电池用正极材料,其制备方法和包含该材料的锂离子电池技术领域本发明涉及锂离子电池领域,尤其涉及一种锂离子电池用正极材料,其制备方法和包含该正极材料的锂离子电池。本发明的尖晶石型含锂锰镍镍复合氧化物的正极材料的表面涂覆有复合涂层,该复合涂层由包含Li 7 La 3的第一涂层组成 Zr 2 O 12 和包含LiNbO 3 的第二涂层。该方法包括:首先在表面上涂覆包含Li 7 La 3 Zr 2 O 12 的第一涂层固相法制备尖晶石型含锂锰镍镍复合氧化物然后通过水热法涂覆第二层包含LiNbO 3 的涂层。本发明的正极材料改善了尖晶石型含锂锰锰镍的复合氧化物的循环稳定性和倍率性能,同时降低了在充电或放电期间电解质对正极材料的溶解和腐蚀作用。

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