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Catalyst support and method for producing porous graphitized carbon material covered with metal nanoparticles

机译:覆盖有金属纳米颗粒的多孔石墨化碳材料的催化剂载体和制备方法

摘要

A known method for producing porous graphitized carbon material covered with metal nanoparticles involves infiltrating a porous template framework of inorganic material with a carbon precursor. After thermal treatment of the precursor, the template is removed and the particulate porous carbon material is covered with a catalytically active substance. According to the invention, in order to keep the proportion of the noble metal loading at a low level, the thermal treatment of the precursor first involves carbonization, and the material is not graphitized into graphitized, particulate, porous carbon material until the template has been removed. The graphitized carbon material has a hierarchical pore structure with a pore volume of at least 0.5 cm3/g and at least 75% of the pore volume is apportioned to macropores with, size 100 to 5000 nm. Before covering with catalytically active substance, the carbon material is subjected to an activation treatment in an oxidizing atmosphere.
机译:制备覆盖有金属纳米颗粒的多孔石墨化碳材料的已知方法包括用碳前体渗透无机材料的多孔模板框架。在对前体进行热处理之后,除去模板,并用催化活性物质覆盖颗粒状多孔碳材料。根据本发明,为了将贵金属负载量的比例保持在较低水平,前体的热处理首先涉及碳化,并且直到模板被模制后,材料才被石墨化为石墨化的,颗粒状的多孔碳材料。删除。石墨化碳材料具有分级的孔结构,其孔体积为至少0.5cm 3 / g,并且至少孔体积的75%分配给尺寸为100至5000nm的大孔。在用催化活性物质覆盖之前,将碳材料在氧化气氛中进行活化处理。

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