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Insensitive plasticizer and melt-castable energetic material

机译:不敏感的增塑剂和可熔铸的高能材料

摘要

A method and compound includes mixing dichloroglyoxime with an alcohol containing an alkyne functional group in methanol to create a mixture; adding a salt compound and water to the mixture to create bis-isoxazole diol; and nitrating the bis-isoxazole diol to create 3,3′-bis-isoxazole-5,5′-bis-methylene dinitrate, which has the structural formula:; embedded image The alcohol containing an alkyne functional group may include propargyl alcohol. The salt compound may include sodium bicarbonate. The method may include nitrating the bis-isoxazole diol with nitric acid. The nitric acid may include at least a concentration of 90% nitric acid in water. Alternatively, the method may include nitrating the bis-isoxazole diol with 100% nitric acid and acetic anhydride. The salt compound and the water may be added to the mixture over at least a six-hour period. The method may include mixing the mixture after adding the salt compound and the water for at least ten hours.
机译:一种方法和化合物,包括在甲醇中将二氯乙二肟与含有炔基官能团的醇混合以形成混合物;然后将二氯乙二肟与含有炔官能团的醇混合。向混合物中加入盐化合物和水,生成双异恶唑二醇。硝化双异恶唑二醇,生成3,3'-双异恶唑-5,5'-双亚甲基二硝酸酯,其结构式为: “嵌入式图像” 含有炔官能团的醇可包括炔丙醇。盐化合物可以包括碳酸氢钠。该方法可以包括用硝酸硝化双-异恶唑二醇。硝酸可包含至少90%浓度的硝酸。或者,该方法可以包括用100%硝酸和乙酸酐硝化双-异恶唑二醇。可以在至少六小时的时间内将盐化合物和水添加到混合物中。该方法可以包括在添加盐化合物和水之后将混合物混合至少十小时。

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