首页> 外国专利> GUEST-COMPOUND-ENVELOPING POLYMER-METAL-COMPLEX CRYSTAL, METHOD FOR PRODUCING SAME, METHOD FOR PREPARING CRYSTAL STRUCTURE ANALYSIS SAMPLE, AND METHOD FOR DETERMINING MOLECULAR STRUCTURE OF ORGANIC COMPOUND

GUEST-COMPOUND-ENVELOPING POLYMER-METAL-COMPLEX CRYSTAL, METHOD FOR PRODUCING SAME, METHOD FOR PREPARING CRYSTAL STRUCTURE ANALYSIS SAMPLE, AND METHOD FOR DETERMINING MOLECULAR STRUCTURE OF ORGANIC COMPOUND

机译:含客体包裹的聚合物-金属-复合晶体,制备方法相同,制备晶体结构分析样品的方法以及确定有机化合物分子结构的方法

摘要

The present invention is a method for preparing a crystal structure analysis sample in which a molecule of an organic compound for which a molecular structure is to be determined, is arranged in pores and voids of a polymer-metal complex crystal in an ordered manner. The method includes immersing a polymer-metal complex crystal including a guest compound in a solvent solution that includes the organic compound, the polymer-metal complex crystal including a guest compound being the polymer-metal complex crystal comprising a polymer-metal complex that comprises a ligand having two or more coordinating moieties. A ratio of an amount of the guest compound (A) present in the pores and the voids to a total amount of the guest compound included in the pores and the voids being 60 mol % or more.
机译:本发明是一种晶体结构分析样品的制备方法,其中将要确定分子结构的有机化合物的分子以有序的方式排列在聚合物-金属络合物晶体的孔隙中。该方法包括将包含客体化合物的聚合物-金属配合物晶体浸入包含有机化合物的溶剂溶液中,包含客体化合物的聚合物-金属配合物晶体是包含聚合物-金属配合物的聚合物-金属配合物晶体,所述聚合物-金属配合物包含有机硅。具有两个或多个配位部分的配体。存在于孔和空隙中的客体化合物(A)的量与包含在孔和空隙中的客体化合物的总量的比率为60mol%以上。

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