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METHOD FOR PREPARING ULTRALOW-TEMPERATURE HIGH-CAPACITY SUPERCAPACITOR AND USE THEREOF

机译:一种超高温高容量超级电容器的制备方法及其用途

摘要

The present invention provides a method for preparing an ultralow—temperature high—capacity supercapacitor. The electrode material used is a composite porous carbon material having micropores and mesopores, and having a specific surface area greater than 2500 mZ/g, Where the pore size of the micropore is larger than 0.8 nm, the pore size of the mesopore is from 2 to 3.0 nm, and the micropores account for above 70%. The electrolytic solution for the supercapacitor is a mixed solvent of l, 3—dioxolane (or methyl formate MF, or a mixture of the two) and acetonitrile, and spiro quaternary ammonium tetrafluoroborate SBP—BF4 is dissolved. The supercapacitor prepared based on the electrode material in combination With the electrolytic solution has a mass specific capacitance greater than 150 F/g and a volume specific capacitance greater than 80 F/cm3 at —lOO°C and a current density larger than 1 A/g.
机译:本发明提供了一种制备超低温高容量超级电容器的方法。所使用的电极材料是具有微孔和中孔且比表面积大于2500mZ / g的复合多孔碳材料,其中,微孔的孔径大于0.8nm时,中孔的孔径为2以下。至3.0nm,并且微孔占70%以上。超级电容器的电解液为1,3-二氧戊环(或甲酸甲酯MF,或两者的混合物)和乙腈的混合溶剂,并溶解了螺四氟硼酸季铵盐SBP-BF4。基于电极材料与电解液组合制备的超级电容器在-100°C下的质量比电容大于150 F / g,体积比电容大于80 F / cm3,电流密度大于1 A / G。

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