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Chiral bicyclic imines based on trans-1,2-diaminocyclohexane and method for producing them
Chiral bicyclic imines based on trans-1,2-diaminocyclohexane and method for producing them
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机译:基于反式1,2-二氨基环己烷的手性双环亚胺及其制备方法
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摘要
the application discloses chiral cyclic imines based on trans - 1,2 - diaminocykloheksanie of general formula 1 in which r is methyl, isopropyl, group: triflurometylowu0105, fenylowu0105, 3 - etylofenylowu0105,4 - tert - butylofenylowu0105 and 1 - naftalenowu0105 intended use in medicine as control measures, inter alia. the cancer cells.these compounds are intended for use in pharmaceutical chemistry and asymmetric synthesis as precursors of medicines.this type of derivatives based on the ring heterocyklicznym, play a huge role as biologically active compounds showing, among others. properties of antibacterial, antiviral agents.the subject application is also a way of chiralnych imin cyclical based on trans - 1,2 - diaminocykloheksanie of general formula 1 in which r is a methyl, isopropyl,triflurometylowu0105, fenylowu0105, 3 - etylofenylowu0105, 4 - tert - butylofenylowu0105 and naftylowu0105 characterised by that (1r, 2r) 1,2 1,3-diaminocyclohexane or (1s, 2s) - 1,2 1,3-diaminocyclohexane,undergo reaction with selected ketoestrami of general formula (2) in which r is a methyl, isopropyl, triflurometylowu0105, fenylowu0105, 3 - etylofenylowu0105, 4 - tert - butylofenylowu0105 and naftylowu0105,at 293 k, in an organic solvent, and the residue is purified.
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