首页> 外国专利> Influence of the viscosity of mixtures of esters based on n-butene by selective use of ethene in the production of previous ester products

Influence of the viscosity of mixtures of esters based on n-butene by selective use of ethene in the production of previous ester products

机译:在以前的酯产品生产中选择性使用乙烯对基于正丁烯的酯混合物的粘度的影响

摘要

Process for obtaining a mixture of esters, in which a mixture of use containing n-butene, whose composition is modified over time, is subjected to a first oligomerization under obtaining an oligomer, and at least a part of the butene oligomers contained in the oligomer are hydroformylated in a hydroformylation to give aldehydes, of which at least a part is hydrogenated by partial hydrogenation in a mixture of alcohols, which is then transformed into the mixture of esters, and in which it determines an approximation of the actual viscosity of the ester mixture, characterized in that, according to the determined approximation of the actual viscosity of the ester mixture, ethene oligomers are selectively added to the butene to hydroformillary oligomers, which are obtained by subjecting a mixture of n-butene-free use, containing ethene, to a second oligomerization carried out separately from the first oligomerization.
机译:获得酯混合物的方法,其中在组成低聚物的情况下,将其组成随时间变化的含正丁烯的混合物进行第一次低聚,并获得低聚物中至少一部分丁烯低聚物在加氢甲酰化反应中进行加氢甲酰化,得到醛,其中至少一部分通过在醇混合物中进行部分加氢而氢化,然后转化为酯混合物,并在其中确定酯的实际粘度的近似值混合物,其特征在于,根据所确定的酯混合物实际粘度的近似值,将乙烯低聚物选择性地添加到丁烯中的加氢甲酸酯低聚物中,所述加氢甲酸酯低聚物是通过将不含乙烯的正丁烯混合物使用而获得的,与第一次低聚反应分开进行第二次低聚反应。

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