Method for producing compound with carbonyl group using ruthenium-carbonyl complex having tridentate ligand as oxidation dehydrogenation catalyst

摘要

A method of producing a compound having a carbonyl group by oxidation dehydrogenation of a reacting compound in the presence of an oxidation dehydrogenation catalyst comprising the ruthenium-carbonyl complex represented by the following general formula (21) RuXY (CO) (L) (21) in the formula X and Y may be the same or different from each other and each represents an anionic ligand and L represents a tridentate amino diphosphine ligand represented by the following general formula (22) ** Formula ** in the formula, R1 , R2, R3 and R4 can be the same or different from each other and each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, an aralkyl group, an alkyloxy group, a cycloalkyloxy group, an aryloxy group, an aralkyloxy group, a heterocyclic group or a substituted amino group, the R1 and R2 and / or R3 and R4 can be linked together to form a ring with an adjacent phosphorus atom, the alkyl group, the cycloalkyl group or, the aryl group, the aralkyl group, the alkyloxy group, the cycloalkyloxy group, the aryloxy group, the aralkyloxy group, the heterocyclic group, and the substituted amino group can have a substituent group, Q1 and Q2 can be the same or different between yes and each represents a divalent alkylene group that may have a substituent group, a divalent cycloalkylene group that may have a substituent group, or a divalent aralkylene group that may have a substituent group, wherein the method is carried out in the absence of a hydrogen acceptor.