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Modified polyaspartic acids, their preparation and their use as dispersing agents and inhibitors of deposition in washing, rinsing and detergent compositions and in the treatment of water

机译:改性聚天冬氨酸,其制备及其在洗涤,漂洗和洗涤剂组合物中以及在水处理中作为分散剂和沉积抑制剂的用途

摘要

Process for the preparation of modified polyaspartic acid or its salts, which comprises the following steps: (i) polycondensation of (a) 50 to 98 mol% aspartic acid, (b) 1 to 49 mol% of at least one compound that it has carboxyl groups, and (c) 1 to 30 mol% of a diamine or an amino alcohol, at a temperature of 100 to 270 ° C for between 1 minute and 50 hours, where (b) is not aspartic acid; (ii) subsequent hydrolysis of the co-condensate with the addition of a base; and (iii) optional acidification with mineral acids of the polyaspartic acid salt obtained in (ii), where the ratio of (b) :( c) is between 5: 1 and 1: 1.5.
机译:制备改性的聚天冬氨酸或其盐的方法,其包括以下步骤:(i)将(a)50至98mol%的天冬氨酸,(b)1至49mol%的至少一种其具有的化合物进行缩聚。羧基;和(c)1至30 mol%的二胺或氨基醇,在100至270°C的温度下保持1分钟至50小时,其中(b)不是天冬氨酸; (ii)随后在加碱的情况下水解缩聚物; (iii)在(ii)中获得的聚天冬氨酸盐的无机酸任选的酸化,其中(b):(c)的比例为5∶1至1∶1.5。

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