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TREATMENT METHOD OF RADIOACTIVE WASTE WATER CONTAINING RADIOACTIVE CESIUM AND RADIOACTIVE STRONTIUM

机译:含放射性铯和放射性锶的放射性废水的处理方法

摘要

The present invention provides a treatment method of radioactive waste watercontaining radioactive cesium and radioactive strontium, comprising passingthe radioactivewaste water containing radioactive cesium and radioactive strontium through anadsorptioncolumn packed with an adsorbent for cesium and strontium, to adsorb theradioactive cesiumand radioactive strontium on the adsorbent, wherein the adsorbent for cesiumand strontiumcomprises: at least one selected from crystalline silicotitanates representedby the generalformulas: Na4Ti4Si3O16.cndot.nH2O, (Na xK(1-x) 4Ti4Si3O16.cndot.mH2O andK4Ti4Si3O16.1H2O wherein xrepresents a number of more than 0 and less than 1, and n, m and 1 eachrepresents a numberof 0 to 8; and at least one selected from titanate salts represented by thegeneral formulas:Na4Ti9O20.cndot.qH2O, (Na yK(1-y) 4Ti9O20.cndot.rH2O and K4Ti9O20.cndot.tH2Owherein y represents a numberof more than 0 and less than 1, and q, r and t each represents a number of 0to 10; wherein theadsorbent is a granular adsorbent having a grain size of 250 µm or more and1200 µm or less,wherein the absorbent is packed to a height of 10 cm or more and 300 cm orless in theadsorption column, and wherein the radioactive waste water is passed throughthe adsorptioncolumn at a linear velocity (LV) of 1 m/h or more and 40 m/h or less and aspace velocity(SV) of 200 h -1 or less.
机译:本发明提供了一种放射性废水的处理方法含有放射性铯和放射性锶,包括放射性含有放射性铯和放射性锶的废水通过吸附填充有铯和锶吸附剂的色谱柱放射性铯和放射性锶在吸附剂上,其中铯的吸附剂和锶包括:至少一种选自以下的结晶硅钛酸盐:由一般分子式:Na4Ti4Si3O16.cnH.O,(Na xK(1-x)4Ti4Si3O16.cnH.O和K4Ti4Si3O16.1H2O,其中x表示大于0且小于1的数字,n,m和1分别代表一个数字0至8;以及至少一种选自以下的钛酸盐:通用公式:Na4Ti9O20.qH2O,(Na yK(1-y)4Ti9O20.rH2O和K4Ti9O20.tH2O其中y代表一个数字大于0且小于1,且q,r和t分别表示数字0至10;其中吸附剂是粒径为250μm以上的粒状吸附剂,1200 µm以下,其中吸收剂被包装到10厘米或更大且300厘米的高度或少在吸附塔,其中放射性废水通过吸附线速度(LV)为1 m / h以上且40 m / h以下的色谱柱空速(SV)为200 h -1以下。

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