首页> 外国专利> CERIA-BASED COMPOSITE FINE PARTICLE DISPERSION, PRODUCTION METHOD THEREFOR, AND POLISHING ABRASIVE GRAIN DISPERSION INCLUDING CERIA-BASED COMPOSITE FINE PARTICLE DISPERSION

CERIA-BASED COMPOSITE FINE PARTICLE DISPERSION, PRODUCTION METHOD THEREFOR, AND POLISHING ABRASIVE GRAIN DISPERSION INCLUDING CERIA-BASED COMPOSITE FINE PARTICLE DISPERSION

机译:基于Ceria的复合细颗粒分散体,制备方法及其对包括Ceria的复合细颗粒分散体的磨料颗粒分散体的抛光

摘要

The present invention addresses the problem of providing a ceria-based composite particle dispersion which is capable of performing polishing at high speed, even for silica films, Si wafers, and difficult to process materials, and which is simultaneously capable of achieving high surface accuracy. The present invention solves the abovementioned problem by providing a ceria-based composite fine particle dispersion which includes ceria-based composite fine particles which have an average particle size of 50-350 nm, and which have the following characteristics. The ceria-based composite fine particles are each provided with: a mother particle; a cerium-containing silica layer; child particles; and a layer including readily soluble silica. The mother particle has amorphous silica as a main component. The child particles have crystalline ceria as a main component. The ratio of the mass of the layer including the readily soluble silica to the mass of the ceria-based composite fine particles is in a specific range. The mass ratio of silica to ceria in the ceria-based composite fine particles is in a specific range. When the ceria-based composite fine particles are subjected to X-ray diffraction, only the crystal phase of the ceria is detected. The average crystallite size of the crystalline ceria measured by subjecting the ceria-based composite fine particles to X-ray diffraction is 10-25 nm.
机译:本发明解决了提供基于二氧化铈的复合颗粒分散体的问题,该二氧化铈类复合颗粒分散体即使对于二氧化硅膜,Si晶片也难以加工,并且能够高速进行抛光,并且同时能够实现高表面精度。本发明通过提供一种二氧化铈类复合微粒分散体来解决上述问题,所述二氧化铈类复合微粒分散体包含平均粒径为50〜350nm,具有以下特征的二氧化铈类复合微粒。所述二氧化铈类复合微粒分别具有:母粒;和含铈的二氧化硅层;儿童颗粒;包括易溶二氧化硅的层。母颗粒具有无定形二氧化硅作为主要成分。子颗粒具有晶体二氧化铈作为主要成分。包含易溶二氧化硅的层的质量与二氧化铈类复合微粒的质量之比在特定范围内。所述二氧化铈类复合微粒中的二氧化硅与二氧化铈的质量比在特定范围内。当对二氧化铈类复合微粒进行X射线衍射时,仅检测到二氧化铈的结晶相。通过对基于二氧化铈的复合微粒进行X射线衍射测定的结晶二氧化铈的平均微晶尺寸为10〜25nm。

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