In a first aspect, the present invention relates to a perovskite material comprising negatively charged layers alternated with and neutralized by positively charged layers; the negatively charged layers having a general formula selected from the list consisting of: Ln-1 MnX3n+1, LnMnX3n+2, and Ln-1M'nX3n+3, and the positively charged layers comprising: - one or more organic ammonium cations independently selected from monovalent cations Q and divalent cations Q', or - a polyvalent cationic conjugated organic polymer Z, wherein Q, Q' and Z comprise each a ττ-conjugated system in which at least 8 and preferably at least 10 atoms participate, L is a monovalent cation, Mn are n independently selected metal cations averaging a valence of two, M'n are n independently selected metal cations averaging a valence equal to 2 + 2/n, X is a monovalent anion, and n is larger than 1.
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机译:在第一方面,本发明涉及一种钙钛矿材料,其包括与带正电的层交替并被其中和的带负电的层。具有以下通式的带负电层:L n I> Sub> -1 Sub> M n I> Sub> X3 n I> Sub> +1 Sub>,L n I> Sub> M < Sub> n I> Sub> X 3 Sub> n I> Sub> +2 Sub>和L n I> Sub> -1 Sub> M' n I> Sub> X 3 Sub> n I> Sub> +3 Sub>,且带正电的层包括:-一个或多个独立地选自单价阳离子Q和二价阳离子Q'的有机铵阳离子,或-多价阳离子共轭有机聚合物Z,其中Q,Q'和Z各自构成一个ττ共轭体系,其中至少8个原子,优选至少10个原子参与,L为单价阳离子,M 是n个平均价为2的独立选择的金属阳离子,M' n Sub>是n个平均价为2 + 2 / n的独立选择的金属阳离子,X是一价阴离子,而< I> n I>大于1。
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