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MOLYBDENUM DOPING-MODIFIED LITHIUM MANGANESE OXIDE COMPOSITE MATERIAL, PREPARATION METHOD THEREFOR AND LITHIUM ION BATTERY
MOLYBDENUM DOPING-MODIFIED LITHIUM MANGANESE OXIDE COMPOSITE MATERIAL, PREPARATION METHOD THEREFOR AND LITHIUM ION BATTERY
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机译:钼掺杂改性氧化锰酸锂复合材料,制备方法及锂离子电池
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摘要
Provided in the present invention is a molybdenum doping-modified lithium manganese oxide composite material, which is molybdenum doping-modified lithium manganese oxide having a surface coated with carbon. The molybdenum doping-modified lithium manganese oxide has a chemical formula represented by formula I: LiMn2-xMoxO4 formula I, wherein 0.01≤x≤0.1; the mass fraction of carbon is 0.1-20%; and the mass fraction of LiMn2-xMoxO4 is 80-99.9%. The present invention uses molybdenum to dope lithium manganese oxide, which may effectively suppress the Jahn-Teller effect in the spinel structure LiMn2O4 as well as the dissolution of manganese, thus improving cycle stability and high temperature performance. Further provided in the present invention is a preparation method for a molybdenum doping-modified lithium manganese oxide composite material. The method has a simple process and costs are low, the method being environmentally friendly and being suitable for large-scale industrial production.
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机译:本发明提供了一种钼掺杂改性的锂锰氧化物复合材料,其为钼掺杂改性的锂锰氧化物,其表面涂覆有碳。钼掺杂改性的锂锰氧化物具有化学式I所示的化学式:LiMn 2-x Sub> Mo x Sub> O 4 Sub> 0.01≤x≤0.1;碳的质量分数为0.1-20%。 LiMn 2-x Sub> Mo x Sub> O 4 Sub>的质量分数为80-99.9%。本发明采用钼掺杂锂锰氧化物,可以有效抑制尖晶石结构LiMn 2 Sub> O 4 Sub>中的Jahn-Teller效应以及锰的溶解,从而提高了循环稳定性和高温性能。本发明还提供了一种钼掺杂改性锂锰氧化物复合材料的制备方法。该方法工艺简单,成本低廉,环境友好,适合大规模工业生产。
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