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Anode for a lithium ion battery cell, method of manufacturing the same, and battery containing the same

机译:锂离子电池单元的负极,其制造方法以及包含其的电池

摘要

TECHNICAL FIELD The present invention relates to a polymer composition for an electrode suitable for forming a lithium ion battery negative electrode, a method for producing the same, and an electrode and a lithium ion battery including the same. The composition comprises an active material comprising a crosslinkable elastomeric binder comprising graphite, an electrically conductive filler and at least one hydrogenated acrylonitrile butadiene copolymer (HNBR) usable in the anode. According to the invention, the binder comprises at least one non-hydrogenated acrylonitrile butadiene copolymer (NBR) having an acrylonitrile content of at least 40% by weight and / or at least one HNBR and is crosslinked by thermal oxidation . This process comprises successively: a) mixing the components of the composition comprising the active material, the binder in the non-crosslinked state and the electrically conductive filler to obtain a precursor mixture of the composition, b) C) applying said mixture to said non-crosslinked film in an oxygen-containing atmosphere at a temperature of from 200 to 300 DEG C in order to form a crosslinked film, Thereby obtaining an electrode.
机译:电极用聚合物组合物,其制造方法以及电极和锂离子电池技术领域本发明涉及适用于形成锂离子电池负极的电极用聚合物组合物,其制造方法以及电极和包括该电极的锂离子电池。该组合物包含活性材料,该活性材料包括可交联的弹性体粘合剂,该粘合剂包括石墨,导电填料和至少一种可用于阳极的氢化丙烯腈丁二烯共聚物(HNBR)。根据本发明,粘合剂包括至少一种丙烯腈含量为至少40重量%的非氢化丙烯腈丁二烯共聚物(NBR)和/或至少一种HNBR,并通过热氧化交联。该方法依次包括:a)混合包含活性材料,处于非交联状态的粘合剂和导电填料的组合物的组分,以获得组合物的前体混合物,b)C)将所述混合物施用于所述非混合物中。在含氧气氛中于200至300℃的温度下进行交联膜形成交联膜,从而获得电极。

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