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A method of extending the useful life of the aged SCR catalyst layer in the exhaust system of the fixed source of NOx

机译:延长NOx固定源排气系统中老化SCR催化剂层使用寿命的方法

摘要

(NO) in the presence of a nitrogen reducing agent in the exhaust gas after the treatment system of the fixed source of NO x so that the exhaust gas discharged from the system to the atmosphere continues to meet the forbidden limits for both NO x and ammonia emissions. x) a dissimilar bovine (a method for N 2) extending the useful life of the aging selective catalytic reduction (SCR) catalyst bed to catalyze the conversion to, the ammonia in the aged SCR catalyst downstream, the exhaust gas also contains oxygen, nitrogen And an additional honeycomb substrate comprising a catalyst for conversion to water (ASC), wherein the catalyst for converting ammonia in the exhaust gas also containing oxygen to nitrogen and water and kNO x of the honeycomb monolith substrates, including at least at 300 to 400 ℃ 80 m / hr, where a 10% H 2 O (steam in air ) KNO x of a sample of catalyst aging at 450 ℃ for 48 hours in the 50 ppm CO, 30 ppm NO, 36 ppm NH 3, 15% O 2, 8% water, 3% CO 2 and the balance N 2 gas composition Is determined by the SCR activity test in a laboratory scale reactor.
机译:NO x 固定源处理系统后,在废气中存在氮还原剂的条件下(NO),以使从系统排放到大气中的废气继续满足禁止 x 和氨气排放的限值。 x)一种不同的牛(N 2的一种方法)延长了老化选择性催化还原(SCR)催化剂床的使用寿命,以催化转化为氨在下游的老化SCR催化剂中,废气中还包含氧气,氮气和另外的蜂窝状基材,该基材包含用于转化为水的催化剂(ASC),其中,用于将废气中的氨转化为氧气,氮和水且kNO <蜂窝状整体基材的Sub> x ,包括至少在300到400℃80 m / hr,其中10%H 2 O(空气中的蒸汽)KNO x 的催化剂样品在50 ppm CO,30 ppm NO,36 ppm NH 3、15%O 2、8%水,3%CO 2中在450℃老化48小时>和余量N 2 气体组成通过实验室规模反应器中的SCR活性测试确定。

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