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Process for the preparation of high purity iridium (III) chloride hydrate

机译:制备高纯度氯化铱(III)水合物的方法

摘要

As a process for producing high purity iridium (III) chloride hydrate, (1) solid H 2 comprising the steps of: providing at least one material selected from the [IrCl 6] hydrate, 1 wt% or more H 2 [IrCl 6] aqueous solution, and solid tetrahydrate IrCl group consisting of; (2) The molar ratio of monohydroxy compound miscible with water in any ratio, primary monoalcohol containing 4 to 6 carbon atoms, and Ir (IV): monohydroxy compound is 1: 0.6 to 1000 One or more monohydroxy compounds selected from the group consisting of secondary monoalcohols containing from 4 to 6 carbon atoms are added to the one or more materials provided in step (1) and are 0.2 to 48 in a temperature range of 20 to 120 ° C. Allowing to react for a time and then removing the volatile components from the reaction mixture formed therefrom.
机译:作为制备高纯度氯化铱(III)水合物的方法,(1)固体H 2 包括以下步骤:提供至少一种选自[IrCl 6] 水合物,1 wt%或更多的H 2 [IrCl 6] 水溶液,和固体四水合物 IrCl组成; (2)与水可混溶的单羟基化合物,含4至6个碳原子的伯一元醇和Ir(IV):单羟基化合物的摩尔比为1∶0.6至1000。一种或多种选自以下的单羟基化合物:将含4至6个碳原子的仲一元醇添加到步骤(1)中提供的一种或多种材料中,并在20至120°C的温度范围内将其添加至0.2至48.允许反应一段时间,然后除去挥发物由由此形成的反应混合物中的组分。

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