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METHOD OF PRODUCING ORGANOMODIFIED MONTMORILLONITE (MMT)

机译:制备有机改性蒙脱土(MMT)的方法

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to a method of modifying inorganic aluminosilicate filler, montmorillonite (clay) MMT using organic water-soluble biodegradable modifiers and can be used in making composites with improved characteristics (high degree of grafting and physical and mechanical properties). It can be used in medicine as biodegradable implants for targeted drug delivery into the body. Method of producing organomodified montmorillonite (MMT) by mixing of MMT previously dispersed in water with water-soluble oxy- or amino acids or their mixtures, lactones or lactams, followed by copolycondensation of component at temperature of 20–100 °C and initial weight ratio of MMT:Modifier:Water=2–30:1.5–50:40–95, with removal of water during copolycondensation. Oxyacids used are lactic or glycolic acid, ε-aminocaproic acid is used as amino acids, lactide, or glycolide, or ε-caprolactone is used as lactones, ε-caprolactam is chosen as lactams.;EFFECT: invention allows reducing the temperature of the grafting process up to room temperature and increasing the degree of grafting of the organic component.;1 cl, 10 dwg
机译:技术领域本发明涉及一种使用有机水溶性生物可降解改性剂改性无机铝硅酸盐填料,蒙脱土(粘土)MMT的方法,并且可用于制备具有改善的特性(高度接枝度和物理机械性能)的复合材料。 )。它可以在医学中用作可生物降解的植入物,用于将药物定向输送到体内。通过将预先分散在水中的MMT与水溶性氧或氨基酸或它们的混合物,内酯或内酰胺混合,然后在20–100°C的温度和初始重量比下将组分共缩聚来生产有机改性蒙脱土(MMT)的方法MMT:Modifier:Water = 2–30:1.5–50:40–95的水,并在共缩聚过程中除去水。所使用的含氧酸是乳酸或乙醇酸,ε-氨基己酸用作氨基酸,丙交酯或乙交酯,或ε-己内酯用作内酯,ε-己内酰胺用作内酰胺;效果:本发明允许降低其温度。接枝过程达到室温,并提高了有机组分的接枝度。; 1 cl,10 dwg

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