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METHOD OF MAKING INORGANIC PEROVSKITE NANOWHISKERS OF CsPbBr3 TYPE

机译:CsPbBr 3 型无机钙钛矿纳米晶的制备方法

摘要

FIELD: nanotechnologies.;SUBSTANCE: invention relates to synthesis of nanostructures based on perovskites, which can be used as materials for nanophotonics to create Fabry-Perot nanosensors and photonic integrated circuits. Method for making insulated perovskite nanowhiskers CsPbBr3 includes treatment of a glass substrate by polishing its surface with a mixture of chromium oxide Cr2O3 particles with diameter less than 100 nm, glyceryl tristearate and oleic acid to create hydrophobic layer, followed by applying a solution of precursors of perovskite CsBr and PbBr2 to the substrate by spraying or spin-coating with formation of solution droplets, then substrate with said application is placed on bottom of vessel, placed in another vessel of larger size, which contains azeotrope: isopropyl alcohol-water (IPA⋅H2O) and is at constant temperature of 50 °C, closing it with a cover and for final formation of nanowhiskers drying is carried out for 5–7 minutes until complete drying of solution drops.;EFFECT: faster operation (production time reduced to 5–7 minutes), simplification and cheapening of manufacturing technology of high-quality inorganic perovskite nanowhiskers of CsPbBr3 type with a longitudinal dimension of 2–50 mcm and a cross section of less than 1 mcm, characterized by low concentration of defect conditions, improved reflectivity of side surfaces and improved optical properties: high Q-factor Q=1,017–6,166 and low generation threshold Pthres=13 nJ/cm2.;1 cl, 6 dwg, 1 ex
机译:技术领域本发明涉及基于钙钛矿的纳米结构的合成,其可以用作纳米光子学的材料以产生法布里-珀罗纳米传感器和光子集成电路。制备绝缘钙钛矿纳米晶须CsPbBr 3 的方法包括通过用氧化铬Cr 2 O 3 的混合物抛光表面来处理玻璃基板直径小于100 nm的三硬脂酸甘油酯和油酸形成疏水层,然后通过喷涂或旋涂将钙钛矿CsBr和PbBr 2 的前体溶液喷涂到基材上,形成溶液液滴,然后将具有上述用途的基材放在容器底部,再放入另一个较大的容器中,该容器中装有恒沸物:异丙醇-水(IPA·H 2 O),并保持恒定温度50°C,盖上盖子,最后形成纳米晶须干燥5–7分钟,直到溶液完全干燥为止。效果:操作更快(生产时间减少到5–7分钟),简化并降低了成本无机钙钛矿粉的制造技术研究CsPbBr 3 型纳米晶须,纵向尺寸为2–50mcm,横截面小于1mcm,其特征在于缺陷条件集中度低,侧面反射率提高和光学特性提高:高Q因子Q = 1,017–6,166和低生成阈值P thres = 13 nJ / cm 2 .; 1 cl,6 dwg,1 ex

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