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METHOD FOR PREPARING POLYAMIDE BY ANION RING-OPENING POLYMERIZATION AND POLYAMIDE PREPARED THEREBY

机译:阴离子开环聚合制备聚酰胺的方法及其制备的聚酰胺

摘要

The present invention relates to a method for preparing a polyamide by anionic ring-opening polymerization and a polyamide prepared thereby, and more particularly, to a method for preparing a polyamide by anionic ring-opening polymerization and a polyamide prepared thereby, wherein the method is an eco-friendly processing method not using a solvent as a catalyst and enables polymerization to a uniform molecular weight with a high conversion rate in a short polymerization reaction time at a low temperature, compared with an existing polymerization method. The method for preparing a polyamide by anionic ring-opening polymerization according to the present invention to attain such a purpose is a method for preparing a polyamide by an anionic polymerization reaction, wherein lactam, and based on 100 parts by weight of the entire lactam, 0.01 parts by weight to 20 parts by weight of an alkali metal as an initiator, 0.3 parts by weight to 10 parts by weight of a molecular weight controller, and 0.002 parts by weight to 1.0 part by weight of carbon dioxide as an activator may be included. As described above, the present invention is directed o an eco-friendly processing method not using a solvent as a catalyst and has an effect that enables polymerization to a uniform molecular weight with a high conversion rate in a short polymerization reaction time at a low temperature, compared with an existing polymerization method
机译:本发明涉及通过阴离子开环聚合反应制备聚酰胺的方法和由此制备的聚酰胺,更具体地,涉及通过阴离子开环聚合反应制备聚酰胺的方法和由此制备的聚酰胺。与现有的聚合方法相比,这是一种不使用溶剂作为催化剂的环保处理方法,并且能够在较短的聚合反应时间内在低温下以高转化率聚合成均一的分子量。为了达到上述目的,根据本发明的通过阴离子开环聚合制备聚酰胺的方法是通过阴离子聚合反应制备聚酰胺的方法,其中内酰胺基于100重量份的全部内酰胺,相对于作为引发剂的20重量份的碱金属为0.01重量份,相对于10重量份的分子量调节剂为0.3重量份,相对于1.0重量份的二氧化碳为0.002重量份的活化剂可以为0.002重量份。包括在内。如上所述,本发明针对不使用溶剂作为催化剂的生态友好的加工方法,并且具有在低温下短的聚合反应时间内能够以高转化率将聚合物聚合成均一分子量的效果。 ,与现有的聚合方法相比

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