首页> 外国专利> SILICONE OIL-TREATED FUMED SILICA, MANUFACTURING METHOD AND APPLICATION THEREOF

SILICONE OIL-TREATED FUMED SILICA, MANUFACTURING METHOD AND APPLICATION THEREOF

机译:硅油处理的气相二氧化硅,制造方法及其应用

摘要

Provided is a silicone oil-treated fumed silica having the following physical properties A) to C) : A) the silicone oil-treated fumed silica has a degree of hydrophobicity of 68 vol% or more; B) the silicone oil-treated fumed silica has a silicone oil fixation rate of from 60 mass% to 95 mass%; and C) a composition obtained by adding 6 parts by mass of the silicone oil-treated fumed silica to 100 parts by mass of an amine composition containing trimethylolpropane polyoxypropylene triamine and 1,3-bis(aminomethyl)cyclohexane at a mass ratio of 95:5 has a viscosity of 4, 000 mPa·s or more after the composition is left to stand at 25°C for 1 hour. The silicone oil-treated fumed silica is preferably obtained by causing a silicone oil to adhere to the surface of fumed silica under an inert gas atmosphere at from 150°C to 300°C, followed by subjecting the fumed silica to high temperature treatment under an oxygen-containing gas atmosphere at from 150°C to 300°C. Also provided are a production method and applications related thereto. When the silicone oil-treated fumed silica of the present invention is mixed with an amine compound, a satisfactory thickening property and satisfactory thickening stability are obtained, and hence the silicone oil-treated fumed silica can also be used for an amine composition for a two-component epoxy-based adhesive. In addition, the silicone oil-treated fumed silica is easily produced at low cost.
机译:提供具有以下物理性质A)至C)的经硅油处理的气相二氧化硅:A)经硅油处理的气相二氧化硅的疏水度为68体积%以上; B)经硅油处理的气相二氧化硅的硅油固着率为60质量%〜95质量%。 C)通过将100质量份含有三羟甲基丙烷聚氧化丙烯三胺和1,3-双(氨基甲基)环己烷的胺组合物按质量比95:6添加6质量份经硅油处理的气相法二氧化硅获得的组合物。将组合物在25℃下放置1小时后,粘度为4,000mPa·s以上。硅油处理的气相二氧化硅优选通过以下方法获得:使硅油在惰性气体气氛中在150℃至300℃下粘附至气相二氧化硅的表面,然后在高温下对气相二氧化硅进行高温处理。从150°C到300°C的含氧气体气氛。还提供了一种生产方法及其相关应用。当将本发明的经硅油处理的气相二氧化硅与胺化合物混合时,获得令人满意的增稠性能和令人满意的增稠稳定性,因此,经硅油处理的气相二氧化硅也可用于两种胺组合物。组分环氧基胶粘剂。另外,容易以低成本生产经硅油处理的气相二氧化硅。

著录项

  • 公开/公告号EP3608381A1

    专利类型

  • 公开/公告日2020-02-12

    原文格式PDF

  • 申请/专利权人 TOKUYAMA CORPORATION;

    申请/专利号EP20180781493

  • 申请日2018-03-27

  • 分类号C09J11/04;C09J163;C08G59/50;

  • 国家 EP

  • 入库时间 2022-08-21 11:39:17

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