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ELECTRON DONOR, AND SYNTHESIS METHOD OF 4,4'-BIPYRIDINE USING ELECTRON DONOR

机译:电子施主,以及使用电子施主的4,4'-联吡啶的合成方法

摘要

To provide an electron donor generated from metal sodium, which can be alternative of a solvent such as conventional ammonia, and further an effective 4,4'-bipyridine synthesis method by a coupling reaction using the electron donor.SOLUTION: There is provided an electron donor containing an electron solvated in DMI by mixing a metal sodium dispersion dispersed in paraffin oil or the like, and 1,3-dimethyl-2-imidazolidinone (DMI). There is further provided an effective synthesis method of 4,4'-bipyridine by reacting the electron donor and bipyridine.SELECTED DRAWING: Figure 7
机译:为了提供由金属钠生成的电子供体,该金属供体可以替代常规氨等溶剂,并通过使用电子供体的偶联反应进一步有效的4,4'-联吡啶合成方法。解决方案:提供了一种电子通过混合分散在石蜡油等中的金属钠分散体和1,3-二甲基-2-咪唑啉酮(DMI),使在DMI中溶剂化的电子的供体。通过给电子体与联吡啶反应,进一步提供了一种有效的4,4'-联吡啶合成方法。选图:图7

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