首页> 外国专利> A method for producing an aqueous dispersion of hollow polymer particles, a method for producing a composition for paper coating, and a method for producing coated paper.

A method for producing an aqueous dispersion of hollow polymer particles, a method for producing a composition for paper coating, and a method for producing coated paper.

机译:一种中空聚合物颗粒的水分散体的生产方法,一种纸涂布用组合物的生产方法以及一种涂布纸的生产方法。

摘要

The present invention includes the following: a core forming step of forming core polymer particles (A) by copolymerizing a monomer mixture (a); a first shell layer forming step of forming a first shell layer (B) which substantially surrounds the core polymer particles (A) and is not swollen by a base by copolymerizing a monomer mixture (b) in the presence of the core polymer particles (A); a core swelling step of swelling the core polymer particles (A) by adding a base to an aqueous dispersion containing the core polymer particles (A) on which the first shell layer (B) has been formed in an amount of 0.1 to 30 parts by weight with respect to a total of 100 parts by weight of a monomer contained in the monomer mixture (a) and the monomer mixture (b); and a shell swelling step of swelling the first shell layer (B) by adding a monomer mixture (c) to an aqueous dispersion containing the core polymer particles (A) on which the first shell layer (B) has been formed in an amount of 0.1 to 45 parts by weight with respect to a total of 100 parts by weight of a monomer contained in the monomer mixture (a) and the monomer mixture (b), in which a difference in water contents represented by (a water content in the core polymer particles (A) on which the first shell layer (B) has been formed after the shell swelling step) - (a water content in the core polymer particles (A) on which the first shell layer (B) has been formed before the shell swelling step) is 1 to 45%.
机译:本发明包括以下步骤:通过共聚单体混合物(a)形成核聚合物颗粒(A)的核形成步骤;第一壳层形成步骤,通过在核聚合物颗粒(A)的存在下使单体混合物(b)共聚,形成基本上包围核聚合物颗粒(A)并且基本不溶胀的第一壳层(B)。 );芯部溶胀步骤是通过将碱添加到包含形成有第一壳层(B)的芯部聚合物颗粒(A)的水性分散体中的0.1至30份(重量)来使芯部聚合物颗粒(A)溶胀。相对于单体混合物(a)和单体混合物(b)中所含的单体的总重量100重量份,为1重量份。壳膨胀步骤,其通过将单体混合物(c)加入到已在其上形成有第一壳层(B)的核聚合物颗粒(A)的水性分散体中的量的第一混合物(c)的溶胀的壳膨胀步骤中。相对于单体混合物(a)和单体混合物(b)中合计100重量份的单体总计0.1〜45重量份,其中水含量之差由(在壳溶胀步骤之后已经形成有第一壳层(B)的核聚合物颗粒(A)-(之前已经形成有第一壳层(B)的核聚合物颗粒(A)中的水含量壳膨胀步骤)为1至45%。

著录项

  • 公开/公告号JP6760301B2

    专利类型

  • 公开/公告日2020-09-23

    原文格式PDF

  • 申请/专利权人 日本ゼオン株式会社;

    申请/专利号JP20170547757

  • 发明设计人 北川 昌;

    申请日2016-10-20

  • 分类号C08F265/06;C08F285;D21H19/42;D21H21/54;

  • 国家 JP

  • 入库时间 2022-08-21 11:33:52

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