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Carbonaceous material for negative electrode active material of nonaqueous electrolyte secondary battery, negative electrode for nonaqueous electrolyte secondary battery, nonaqueous electrolyte secondary battery, and method for producing carbonaceous material
Carbonaceous material for negative electrode active material of nonaqueous electrolyte secondary battery, negative electrode for nonaqueous electrolyte secondary battery, nonaqueous electrolyte secondary battery, and method for producing carbonaceous material
A problem to be solved by the present invention is to provide a carbonaceous material suitable for a negative electrode active material for non-aqueous electrolyte secondary batteries (e.g., lithium ion secondary batteries, sodium ion secondary batteries, lithium sulfur batteries, lithium air batteries) having high charge/discharge capacities and preferably high charge/discharge efficiency as well as low resistance, a negative electrode comprising the carbonaceous material, a non-aqueous electrolyte secondary battery comprising the negative electrode, and a production method of the carbonaceous material. The present invention relates to a carbonaceous material having a nitrogen element content of 1.0 mass % or more and an oxygen content of 1.5 mass % or less obtained by elemental analysis, a ratio of nitrogen element content and hydrogen element content (RsubN/H/sub) of 6 or more and 100 or less, a ratio of oxygen element content and nitrogen element content (RsubO/N/sub) of 0.1 or more and 1.0 or less, and a carbon interplanar spacing (dsub002/sub) observed by X-ray diffraction measurement of 3.70 Å or more.
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机译:本发明要解决的问题是提供一种适合用于非水电解质二次电池(例如锂离子二次电池,钠离子二次电池,锂硫电池,锂空气电池)的负极活性物质的碳质材料。具有高充电/放电容量并且优选地具有高充电/放电效率并且具有低电阻的负极,包括碳质材料的负极,包括负极的非水电解质二次电池以及碳质材料的制造方法。本发明涉及通过元素分析得到的氮元素含量为1.0质量%以上,氧含量为1.5质量%以下的碳质材料,氮元素含量与氢元素含量之比(R N N / H sub>)为6以上且100以下,氧元素含量与氮元素含量之比(R O / N sub>)为0.1以上且1.0以下,并且X射线衍射测量的3.70Å或更大的碳平面间距(d 002 sub>)。
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